The empirical formula's of the two glazes are identical except for the replacement of MgO in the first glaze with CaO in the second glaze.
The first glaze has CaO only as an impurity in other materials.
These are cone 6 glazes, nevertheless, the high MgO glaze is considerably more fused, and is a full gloss glaze.
The high CaO glaze, resulting from replacement of MgO with CaO, is a nearly dry matt.