variations on a saturated iron glaze

firing to cone 10 in oxidation

A half hour hold at 1850 deg F

slow downfire at 50 deg F an hour in the interval 1850 deg F to 1700 deg F

slow downfire at 25 deg F an hour in the interval 1700 deg F to 1650 deg F

One hour hold at 1650 deg F



Variations on a saturated iron glaze

Here are small variations of the glaze iron_8_Right_162_1Z_1 which has massed golden crystals and metallic luster.

The Ur glaze iron_8_R_162_1Z_1

full view

We test nearby compositions, to see how rapidly its appearance changes, and to understand in which directions its appearance changes most rapidly.

The perterbations of each glaze from the Ur glaze (iron_8_Right_162_1Z_1) are:

increase or decrease Alumina

increase Alumina and Silica

increase silica

increase or decrease alkali metals
(with a corresponding decrease in alkaline earths)

the glittery look of metallic crystals is no easily visible in a motionless pot seen by a non-moving observer, which is what one has in a photograph.
For this reason we show here a close up of a small cluster of metallic crystals to enable their identification in the pictures that follow.

small clusters of metallic crystals

full view

We show close up images of the above variations of our Ur glaze.

glaze composition

The Ur glaze is high in alkaline metals and in Li2O, with Al2O3 = .5, SiO2 = 3.15 and P2O5 = .04.
The variants are all high in alkali metals and Li2O. Al2O3 varies from .44 to .6, and Silica from 2.8 to 3.5. P2O5 remains .04.



increased and decreased Alumina

The image on the left shows the result of a small increase in Alumina, on the right a small decrease.
Neither looks quite like the original. Surprisingly increasing alumina seemed to increase the abundance of metallic crystals.
As that is contrary to expectation and the effect is small we conclude that this glaze is relatively insensitive to small changes in alumina.



A leaf

full view

This is a leaf print on satIron_ZG_0, the glaze with added alumina.
the wash is custer feldspar with rutile added.

The painterly quality of this leaf print, in contrast to the image on the Ur glaze shows a greater migration of properties than we'd suspected.
In the upper left corner there is a small amount of a variant glaze visible.



increase of silica, and of both silica and alumina

The glaze on the left has a small addition of silica to the Ur glaze,
that on the right a small addition of both silica and alumina.
Again we note that contrary to intuition, increasing both silica and alumina seemed to increase the dominance of metallic crystals.
Putting this together with the above, and the smallness of the effect
we are tempted to think this glaze varies slowly with increases of alumina and silica, together or independantly.



increase or decrease of alkali metals

The glaze shown on the left has some alkaline earths replaced with alkali metals (K2O, Na2O, Li2O), the one on the right the reverse, some alkali metals replaced with alkaline earths.

Here we see the first substantial shift in properties, an increase in alkali metals gives a glaze with a dense coverage of metallic crystals.

decreasing the alkali metals removes visible metallic crystals.



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