Neighbor glazes

firing to cone 10 in oxidation

The Downfire profile

A half hour hold at 1750 deg F

A three hour hold at 1700 deg F

slow downfire at 25 deg F an hour in the interval 1700 deg F to 1650 deg F

A one hour hold at 1650 deg F

Clay body is a grolleg porcelain from Tacoma Clay Art Center.

composition of the two glazes

These are both high alkali metal saturated iron glazes

Emperical Formula satIron_ZJ_1:
K2O 0.01
Na2O 0.52
Li2O 0.25
CaO 0.15
MgO 0.07

Al2O3 .52
Fe2O3 .22
SiO2 3.26
P2O5 .038

Emperical Formula satIron_ZJ_1PP:
K2O 0.01
Na2O 0.47
Li2O 0.23
CaO 0.23
MgO 0.06

Al2O3 .47
Fe2O3 .2
SiO2 2.94
P2O5 .067

back story

The intent had been to test only the glaze satIron_ZJ_1, however, a weighing error, adding Bone ash twice leaving me with the glaze satIron_ZJ_1PP.
As I had the weighed glaze, with known composition, it was too much temptation to think I'd throw it away rather than test, so that's what I did.

Note that the second glaze with 3 % extra bone ash differs slightly in several oxides, most notably, higher P2O5,
though the extra CaO increased the base (flux) content of the glaze, giving lower Alumina and Silica as well.

In the first firing the fired difference between these two glazes was spectacular, and ought to have been a warning -
the compositional difference is insufficient to warrant that huge a change.
Therefore one concludes that both glazes are greatly influenced by details of glaze application and firing conditions.
As it happens in the first firing, these two glazes were next to each other on the same shelf in the kiln.

I show here the two glazes in the first firing, and the second glaze in a subsequent firing.
Both firings were in the same kiln, with the same firing protocol, with near identical fired orton cones.



The Two glazes in the first firing:

full view

satIron_ZJ_1 on a 3.5 inch diameter bowl

full view

satIron_ZJ_1PP on a 3.5 inch diameter bowl



The secon glaze only in the second firing

full view

satIron_ZJ_1PP on a plate 9 inches in diameter



commentary

The first glaze, satIron_ZJ_1 has a waxy matt texture, and is a mixture of various shades of brown with only hints of bright red and orange.

The second glaze, satIron_ZJ_1PP, with the extra bone ash, in the first firing is a full gloss,
and where the glaze application is sufficiently thick, is a fiery mix of yellows, oranges and reds.

This same glaze, in the second firing is a waxy gloss, where the glaze application is thick has a lusterous metallic surface film,
the fiery oranges are nearly gone, except on the upper rim
where the plate is thin.



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