Effects of Firing

I show the effect of three different firing protocols on a glaze with metallic surface crystals and leopard spots.

Two of these firing have slowed cooling for temperatures above 1900 deg F and slightly below turn-down. My kiln will normally cool to 1900 deg F
in ~ an hour and a half. Instead, in the two experimental firings, the time in this interval is increased to ~ 4 hours.
The third firing is a control: it is allowed to cool normally, the slow ramps and holds are below 1750 deg F.

The firing protocol for the first firing started its retarded cooling too high - that together with the hold there
resulted in a cone 11 firing. The second firing was adjusted to avoid that problem.

The metallic surface crystals are micro-crystals. The black leopard spots are likely also crystals, as also the sharply defined
red/yellow/orange dendritic like lacy patterns. The slow cooling in a region where crystal growth is rapid facilitated the growth of
large, coarse crystals.

The difference in result between the first two firings, both with slower cooling above 1900 deg F were small compared to
the difference between the result in either of these firings and the third firing. The extra time in the temperature interval
below turn down and 1900 Deg F is more significant for this glaze than final cone reached.

oxidation firing in an electric kiln

Firing profiles

The three firings have the same Up Fire Profile, which is given here:

Up Fire profile

150 deg F an hour to 250 deg F

400 deg F an hour to 1800 deg F

300 deg F an hour to 2050 deg F

120 deg F an hour to 2310 deg F with a hold of 20 minutes at 2310 deg F

There are three distinct down fire protocols, given here:

Down Fire Profile 1

300 deg F hr to 2285 deg F then hold 30 minutes

100 deg F hr to 1900 deg F

300 deg F an hour to 1750 deg F then a half hour hold at 1750 deg F

300 deg F an hour to 1700 deg F then a Two hour hold at 1700 deg F

300 deg F an hour to 1600 deg F then a two hour hold at 1600 deg F

This was a cone 11 firing.

Down Fire Profile 2

300 deg F hr to 2210 deg F then hold 30 minutes

80 deg F hr to 1900 deg F

300 deg F an hour to 1750 deg F then a half hour hold at 1750 deg F

300 deg F an hour to 1700 deg F then a Two hour hold at 1700 deg F

300 deg F an hour to 1600 deg F then a two hour hold at 1600 deg F

This was a cone 10 firing.

Down Fire Profile 3

300 deg F an hour to 1750 deg F then a half hour hold at 1750 deg F

300 deg F an hour to 1700 deg F then a Three hour hold at 1700 deg F

300 deg F an hour to 1600 deg F then a two hour hold at 1600 deg F

This was a cone 10 firing.

Clay body is a grolleg porcelain from Tacoma Clay Art Center.

glaze composition

Empirical Formula glaze satIron_mashiko_neph_1I_0 :

K2O        .1
Na2O        .1
Li2O        .29
CaO        .5
MgO        .01

Al2O3        .66
Fe2O3        .24

SiO2        4.04
P2O5        .17

molecular percent Silica 66%



The inside of the pot is shown on the left; the outside on the right.

First Firing

Cone 11 and slow cooling from below top to 1900 deg F.



Second Firing

cone 10 and slow cooling from below top to 1900 deg F



Third Firing

cone 10 and no slowdown in cooling above 1900 Deg F



bowls are ~ 4 inches in diameter



Remarks

Light reflected off the metallic surface crystals causes the diffuse fragmented white fog. The light is not reflected sharply
as it would be off a mirror or glassy surface.

The glaze cooled slowly above 1900 deg F, shows more varied colors, a variety of oranges and reds, and has halos surrounding the leopard spots.
In the faster-cooled glaze, the background color, is more uniform.

For these saturated iron glazes high in Phosphorus, it seems that a hotter firing - more heat work - results in less dramatic metallic crystal growth.

faster cooling above 1900 deg F results in less dramatic metallic crystal growth.

Thinner glaze application results in less dramatic metallic crystal growth.

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