Granular Phosphorus

Here is a high phosphorus, high alkali metal glaze, with a non-glossy surface, and a mottled texture resulting from the uneven distribution
of the large TSP (trisodium phosphate) crystals in the glaze slurry.

Glaze satIron_ZG_1P_1

full view

inside of bowl:



full view

Outside of bowl:



bowl is ~3 inches in diameter



oxidation firing to cone 10 in an electric kiln

Firing profiles

Up Fire profile

150 deg F an hour to 250 deg F

400 deg F an hour to 1800 deg F

300 deg F an hour to 2050 deg F

120 deg F an hour to 2300 deg F with a hold of 20 minutes at 2300 deg F

Down Fire Profile

300 deg F an hour to 1750 deg F then a half hour hold at 1750 deg F

300 deg F an hour to 1700 deg F then a Three hour hold at 1700 deg F

25 deg F an hour to 1650 deg F then a one hour hold at 1650 deg F

Clay body is a grolleg porcelain from Tacoma Clay Art Center.

glaze compositions

Empirical Formula glaze satIron_ZG_1P_1 :

The glaze with .12 molecular fraction Phosphorus

K2O        .15
Na2O        .4
Li2O        .21
CaO        .1
MgO        .14

Al2O3        .52
Fe2O3        .19

SiO2        3.2
P2O5        .12

molecular percent Silica 63.6%



Remarks

This glaze has a heavily textured dark stony surface with variegated red orange blooms in regions where phosphate granules are concentrated.

The striking orange-y blooms are the result of a non-uniform distribution of trisodium phosphate in the glaze.

Another consequence of the uneven distribution of the trisodium phosphate within the glaze slurry is the stony surface as it
also causes an uneven distribution of sodium within the glaze. The TSP carries a goodly quantity of sodium along
with its phosphate.

In a prior test we have seen that without the phosphorus there are no golden metallic crystals.

As expected, these crystals are found in satIron_ZG_1P_1 in regions of high phosphorus concentration.
In that prior test, satIron_ZG_0 has a full gloss surface as is expected of a high alkaline metal glaze.
Therefore, the stony surface of satIron_ZG_1P_1 is a surprise given its high alkali metal content.

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