Metallic microCrystals

The Initial glaze - the starting point for this note: is the Glaze satIron_ZG_1O_0

The surface of this glaze is covered in metallic micro crystals.

full view



Glaze satIron_ZG_1O_1Q_0

This glaze has few metallic micro crystals.

It contains less silica.

full view



Glaze satIron_ZG_1O_1

This glaze also has few metallic micro crystals

This glaze has more CaO and less MgO than satIron_ZG_1O_0

full view



bowl are ~3 inches in diameter



oxidation firing to cone 10 in an electric kiln

Firing profiles

Up Fire profile

150 deg F an hour to 250 deg F

400 deg F an hour to 1800 deg F

300 deg F an hour to 2050 deg F

120 deg F an hour to 2300 deg F with a hold of 20 minutes at 2300 deg F

Down Fire Profile

300 deg F an hour to 1750 deg F then a half hour hold at 1750 deg F

300 deg F an hour to 1700 deg F then a Three hour hold at 1700 deg F

25 deg F an hour to 1650 deg F then a one hour hold at 1650 deg F

Clay body is a grolleg porcelain from Tacoma Clay Art Center.

glaze compositions

Initial glaze

Empirical Formula satIron_ZG_1O_0 :

K2O        .25
Na2O        .24
Li2O        .24
CaO        .17
MgO        .1

Al2O3        .52
Fe2O3        .21

SiO2        3.2
P2O5        .05

molecular percent Silica 64%



Glaze with less silica

Empirical Formula glaze satIron_ZG_1O_1Q_0 :

K2O        .2
Na2O        .3
Li2O        .23
CaO        .17
MgO        .1

Al2O3        .52
Fe2O3        .2

SiO2        3
P2O5        .04

molecular percent Silica 63%



Glaze with CaO replacing MgO

Empirical Formula glaze satIron_ZG_1O_1 :

K2O        .25
Na2O        .24
Li2O        .24
CaO        .26
MgO        .01

Al2O3        .52
Fe2O3        .21

SiO2        3.18
P2O5        .05

molecular percent Silica 64%



Remarks

These glazes are waxy microcrystalline glazes.

Distinct crystals grow in a glaze and compete for resources. These three glazes contain the same components in different proportions.
What determines when the metallic micro crystals appear?

The low silica glaze surface has a somewhat lumpy surface, an indication of high viscosity.
Decreasing silica in a glaze can decrease or increase viscosity of the glaze.
In this case decreased silica increased the viscosity.

Movement of materials within this glaze will be slower as a result of its higher viscosity. This slowed transport favors
the growth of crystals from local materials, while retarding the accumulation of distant particles.
Perhaps this indicates a dependance of the metallic micro crystals on distant particles.

The glaze which is lower in MgO is thereby higher in CaO. The MgO may be important to the crystal growth, alternatively,
the additional CaO which substituted for the MgO provides the opportunity for calcia rich crystals to form at the expense
of the metallic crystals.

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