Leopard Spots

I refer to a glaze which has dark spots on a light background as a Leopard Spot glaze.

A leopard spot glaze satIron_mashiko_neph_1H_0 is shown here:

Leopard Spot Glaze

satIron_ZG_1S_1MMg, seen here, has a distinct composition and appearance.

I show clos-ups of the spots and, for context, a picture of the pot.



Close up Images of the spots

full view

full view



Image of the piece

full view

bowl with glaze satIron_ZG_1S_1MMg

small bowl ~4 inches in diameter



oxidation firing to cone 10 in an electric kiln

Firing profiles

Up Fire profile

150 deg F an hour to 250 deg F

400 deg F an hour to 1800 deg F

300 deg F an hour to 2050 deg F

120 deg F an hour to 2310 deg F with a hold of 20 minutes at 2310 deg F

Down Fire Profile

300 deg F an hour to 1750 deg F then a half hour hold at 1750 deg F

300 deg F an hour to 1700 deg F then a Three hour hold at 1700 deg F

25 deg F an hour to 1650 deg F then a one hour hold at 1650 deg F

Clay body is a grolleg porcelain from Tacoma Clay Art Center.

glaze composition

Empirical Formula satIron_ZG_1S_1MMg :

K2O        .16
Na2O        .41
Li2O        .21
CaO        .21
MgO        .01

Al2O3        .53
Fe2O3        .2

SiO2        3.27
P2O5        0.18

molecular percent Silica 63%





Remarks

Although this glaze, satIron_ZG_1S_1MMg, and the prior glaze satIron_mashiko_neph_1H_0 show dark spots on a light background,
the two glazes are not similar in appearance; the spots on SatIron_ZG_1S_1MMg are raggedy, and the background is
metallic and gold colored. This is not surprising as these two glazes have little in common other than high Iron,
equal silica:alumina ratio, and high phosphorus.

Dark spots on a light background is a particular form of phase separation in the liquid melt at the point when the liquid solidifies.
It is a kind of behavior of the melt, which is not specific to a particular composition.

Leopard spots are not easily reproducible, as small changes in the firing protocol, or glaze application thickness can reduce
the size of the spots to near invisibility.

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