Breaking Colors - Leopard Spots

The glaze leopard_Z1T has two predominant colors, a lusterous brown-black, and a metallic gold speckled orangy-brown.
As these two colors are sharply delineated from each other, I call this a breaking color. It is also a leopard spot glaze as it has
dark spots on a light background, though some of the spots merge.

The glaze leopard_Z1T is the third in a series of glazes, the first two of which were leopard_Z1R, followed by leopard_Z1S.

I show close-ups of the spots and markings of the glaze leopard_Z1T and, for context, a picture of the pot.

Images of the two preceding glazes in the series, leopard_Z1R and leopard_Z1S are shown to give an indication of the
influence of compositional variations in this particular glaze family.



Close-up Images of the markings on leopard_Z1T

full view

full view



Image of the piece

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image of predecessors

full view

bowl with glaze leopard_Z1R



full view

bowl with glaze leopard_Z1S

all pieces shown are small bowls ~4 inches in diameter



oxidation firing to cone 10 in an electric kiln

Firing profiles

Up Fire profile

150 deg F an hour to 250 deg F

400 deg F an hour to 1800 deg F

300 deg F an hour to 2050 deg F

120 deg F an hour to 2300 deg F with a hold of 20 minutes at 2300 deg F

Down Fire Profile

300 deg F an hour to 1750 deg F then a half hour hold at 1750 deg F

300 deg F an hour to 1700 deg F then a Three hour hold at 1700 deg F

25 deg F an hour to 1650 deg F then a one hour hold at 1650 deg F

Clay body is a grolleg porcelain from Tacoma Clay Art Center.

glaze compositions

Empirical Formula leopard_Z1T :

K2O        .06
Na2O        .40
Li2O        .19
CaO        .34
MgO        .01

Al2O3        .76
Fe2O3        .26

SiO2        4.12
P2O5        0.17

molecular percent Silica 65%



Empirical Formula leopard_Z1R :

K2O        .06
Na2O        .38
Li2O        .2
CaO        .34
MgO        .02

Al2O3        .66
Fe2O3        .28

SiO2        4.3
P2O5        0.16

molecular percent Silica 67%



Empirical Formula leopard_Z1S :

K2O        .1
Na2O        .42
Li2O        .21
CaO        .25
MgO        .02

Al2O3        .76
Fe2O3        .27

SiO2        4
P2O5        0.17

molecular percent Silica 64%





Remarks

The first glaze in this series, leopard_Z1R has a bronze colored background with metalic micro-crystals and dark spots.
The dark spots are small and easily missed

The next glaze in the series, leopard_Z1S, is a lusterous brown-black. It has prominent pinholes as a result of its high viscosity
and thick glaze application.

The composition of leopard_Z1S differs from that of leopard_Z1R by having higher alkali metals and higher alumina.
Some of the CaO was replaced by alkali metals. then the molecular fraction of alumina was raised to retain the same value for the
alkali metal:alumina ratio, as that of leopard_Z1R.

The third glaze in the series, leopard_Z1T has large high contrast spots in a matrix of metallic speckled orange brown. It also has high viscosity
so crawls readily.

The composition of the glaze leopard_Z1T is a cross between leopard_Z1R and leopard_Z1S. It has the bases of leopard_Z1R
(i.e. the higher CaO and lower alkali metals); as well as the higher alumina of leopard_Z1S.

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