Phosphorus and Texture

Phosphorus added to a purple glaze created a metallic micro-crystalline bronze glaze.

The second glaze was generated from the first by the addition of phosphorus, turning a sedate purple adventurine glaze
into a bronze glaze with surface dominated by metallic golden micro-crystals.

Glaze iron_8_R_C10_13PSi

The original glaze without phosphorus.

This is a full gloss dark purple black with a dusting of silvery red crystals, that sparkles in bright light.

full view

bowl is ~3 inches in diameter



Glaze iron_8_R_C10_13PSi_PP

glaze with added Phosphorus.

This is a yellowish brown glaze with a metallic undertone, its surface is largely covered in varigated metallic microcrystals.
The dominant color of the micro-crystals is golden yellow, though there are reds greens and blacks, as well.
Depending on the lighting, there is a distinct hint of lusterous opalescence which contributes to the multicolored effect.

The white flecks on the outside of the pot are reflections off of pinholes in the glaze.

full view

full view

bowl is ~3 inches in diameter



oxidation firing to cone 10 in an electric kiln

Firing profiles

Up Fire profile

150 deg F an hour to 250 deg F

400 deg F an hour to 1800 deg F

300 deg F an hour to 2050 deg F

120 deg F an hour to 2310 deg F with a hold of 20 minutes at 2300 deg F

Down Fire Profile

300 deg F an hour to 1750 deg F then a half hour hold at 1750 deg F

300 deg F an hour to 1700 deg F then a Three hour hold at 1700 deg F

25 deg F an hour to 1650 deg F then a one hour hold at 1650 deg F

Clay body is a grolleg porcelain from Tacoma Clay Art Center.

glaze compositions

Empirical Formula Glaze iron_8_R_C10_13PSi

K2O        .11
Na2O        .45
Li2O        .25
CaO        .17
MgO        .02

Al2O3        .56
Fe2O3        .28

SiO2        3.12

molecular percent Silica 63%



Empirical Formula glaze iron_8_R_C10_13PSi_PP :

K2O        .11
Na2O        .45
Li2O        .25
CaO        .17
MgO        .02

Al2O3        .56
Fe2O3        .28

SiO2        3.12
P2O5        .04

molecular percent Silica 62%



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