Reactions between abutting glazes

The interaction between two adjacent glazes.

Closeups of the interaction region of the two glazes are shown and, for context, a picture of the pot.

The design is created by painting rubber latex on the bisque pot then after the latex has cured, applying the main glaze. After drying,
the latex is removed and the open area filled in with a second glaze.



Close up Images of the interaction region

full view

full view

full view



Image of the piece

full view

bowl with glaze paleGreyYellow and inlay copperYellow_Z24_0

bowl is ~9 inches in diameter



oxidation firing to cone 10 in an electric kiln

Firing profiles

Up Fire profile

150 deg F an hour to 250 deg F

400 deg F an hour to 1850 deg F

120 deg F an hour to 2130 deg F

13 deg F an hour to 2180 deg F then a two hour hold at 2180 deg F

13 deg F an hour to 2220 deg F then a three hour hold at 2220 deg F

Down Fire Profile

300 deg F an hour to 1750 deg F then a half hour hold at 1750 deg F

300 deg F an hour to 1700 deg F then a Three hour hold at 1700 deg F

25 deg F an hour to 1650 deg F then a one hour hold at 1650 deg F

Clay body is a grolleg porcelain from Tacoma Clay Art Center.

glaze compositions

Background glaze

Empirical Formula paleGreyYellow :

K2O        .08
Na2O        .03
CaO        .71
MgO        .18

Al2O3        .45
Fe2O3        .06

SiO2        2.46

molecular percent Silica 61.8%



Inlay Glaze

Empirical Formula glaze copperYellow_Z24_0 + 1% copper carbonate :

K2O        .13
Na2O        .42
CaO        .24
MgO        .11
ZnO        .1

Al2O3        .71

SiO2        3.25

molecular percent Silica 65.5%





Remarks

The background glaze contains Iron Oxide, the foreground or inlay glaze contains copper carbonate.
Yet the interaction of these two glazes contains a sharply delimited opaque matte white band. The width of this band is
independant of the width of the inlay.

What is it, and how did that happen?

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