Phosphorus added to a silvery oil spot glaze created a multicolored
iron glaze.
The second glaze differs from the first primarily in the inclusion of phosphorus.
A micro-crystalline silvery glaze morphed
The original glaze without phosphorus.
This is satiny silver with dark oil spots and a brown rim.
The metallic surface crystals form a thin surface layer, which
is absent in a thin glaze application.
glaze containing phosphorus.
The surface is a varigated splatter of iron colors, while the volcanic
erruptions just prior to maturation produced the silvery oil spots.
Dependant on the lighting, there is a distinct hint of lusterous
opalescence which contributes to the multicolored effect.
The silvery oil spot glaze family, of which mashiko_ZS_T_5 is a member mature
precipitously, in a small temperature window.
Phosphorus being a glass former, likely raises the temperature at which the
chemical reactions finish, and the glaze settles down
150 deg F an hour to 250 deg F
400 deg F an hour to 1800 deg F
300 deg F an hour to 2050 deg F
120 deg F an hour to 2310 deg F with a hold of 20 minutes at 2300 deg F
300 deg F an hour to 1750 deg F then a half hour hold at 1750 deg F
300 deg F an hour to 1700 deg F then a Three hour hold at 1700 deg F
25 deg F an hour to 1650 deg F then a one hour hold at 1650 deg F
K2O .15
Al2O3 .83
SiO2 5.9
molecular percent Silica 74%
K2O .14
Al2O3 .83
SiO2 5.7
molecular percent Silica 73%
into a glaze with
surface dominated by iron colors of many hues.
Glaze mashiko_ZS_T_5
If broken, a layer of metallic silver
atop a thick glossy brown substrate is seen in the cross section of the pot
wall.
bowl is ~3 inches in diameter
Glaze mashiko_ZJ_PP_Z2A
These
are a remnant of the metallic surface crystals of the above glaze,
mashiko_ZS_T_5. The late boiling created differential flow within the glaze
and segregation of the glaze components, thus the eccentric scattering of
colors.
The glazes are reacting
rapidly near maturation, these chemical reactions involve boiling, thus the
oil spots.
with a smooth
surface. The result, mashiko_ZJ_PP_Z2A didn't quite finish settling down.
mug is ~5 inches in high
oxidation firing to cone 10 in an electric kiln
Firing profiles
Up Fire profile
Down Fire Profile
Clay body is a grolleg porcelain from Tacoma Clay Art Center.
glaze compositions
Empirical Formula Glaze mashiko_ZS_T_5
Na2O .11
Li2O .11
CaO .26
MgO .37
Fe2O3 .22
Empirical Formula glaze mashiko_ZJ_PP_Z2A :
Na2O .13
Li2O .1
CaO .26
MgO .37
Fe2O3 .21
P2O5 .05