Phosphorus and Color

Phosphorus added to a silvery oil spot glaze created a multicolored iron glaze.

The second glaze differs from the first primarily in the inclusion of phosphorus. A micro-crystalline silvery glaze morphed
into a glaze with surface dominated by iron colors of many hues.

Glaze mashiko_ZS_T_5

The original glaze without phosphorus.

full view

This is satiny silver with dark oil spots and a brown rim.

The metallic surface crystals form a thin surface layer, which is absent in a thin glaze application.
If broken, a layer of metallic silver atop a thick glossy brown substrate is seen in the cross section of the pot wall.

bowl is ~3 inches in diameter



Glaze mashiko_ZJ_PP_Z2A

glaze containing phosphorus.

full view

The surface is a varigated splatter of iron colors, while the volcanic erruptions just prior to maturation produced the silvery oil spots.
These are a remnant of the metallic surface crystals of the above glaze, mashiko_ZS_T_5. The late boiling created differential flow within the glaze
and segregation of the glaze components, thus the eccentric scattering of colors.

Dependant on the lighting, there is a distinct hint of lusterous opalescence which contributes to the multicolored effect.

The silvery oil spot glaze family, of which mashiko_ZS_T_5 is a member mature precipitously, in a small temperature window.
The glazes are reacting rapidly near maturation, these chemical reactions involve boiling, thus the oil spots.

Phosphorus being a glass former, likely raises the temperature at which the chemical reactions finish, and the glaze settles down
with a smooth surface. The result, mashiko_ZJ_PP_Z2A didn't quite finish settling down.

mug is ~5 inches in high



oxidation firing to cone 10 in an electric kiln

Firing profiles

Up Fire profile

150 deg F an hour to 250 deg F

400 deg F an hour to 1800 deg F

300 deg F an hour to 2050 deg F

120 deg F an hour to 2310 deg F with a hold of 20 minutes at 2300 deg F

Down Fire Profile

300 deg F an hour to 1750 deg F then a half hour hold at 1750 deg F

300 deg F an hour to 1700 deg F then a Three hour hold at 1700 deg F

25 deg F an hour to 1650 deg F then a one hour hold at 1650 deg F

Clay body is a grolleg porcelain from Tacoma Clay Art Center.

glaze compositions

Empirical Formula Glaze mashiko_ZS_T_5

K2O        .15
Na2O        .11
Li2O        .11
CaO        .26
MgO        .37

Al2O3        .83
Fe2O3        .22

SiO2        5.9

molecular percent Silica 74%



Empirical Formula glaze mashiko_ZJ_PP_Z2A :

K2O        .14
Na2O        .13
Li2O        .1
CaO        .26
MgO        .37

Al2O3        .83
Fe2O3        .21

SiO2        5.7
P2O5        .05

molecular percent Silica 73%



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