Reactions at the interface between two glazes

The interaction at the interface of adjacent glazes.

Several closeups of the interaction region of the two glazes are shown and, for context, a picture of the pot.

The background glaze is satIron_ZG_Ip7_5, the foreground design is glazed with alexanderBowl_0_Z1Y.

The design is created by adhering a mask and then applying the main glaze. After drying, the entire pot is coated in wax,
then the mask is removed and the open area filled in with a second glaze.



Close up Images of the interaction region

full view

full view

full view



Image of the piece

full view

bowl with glaze satIron_ZG_Ip7_5 and inlay alexanderBowl_0_Z1Y

bowl is ~10 inches in diameter



oxidation firing to cone 10 in an electric kiln

Firing profiles

Up Fire profile

150 deg F an hour to 250 deg F

400 deg F an hour to 1800 deg F

300 deg F an hour to 2050 deg F

120 deg F an hour to 2310 deg F with a hold of 20 minutes at 2310 deg F

Down Fire Profile

300 deg F an hour to 1750 deg F then a half hour hold at 1750 deg F

300 deg F an hour to 1700 deg F then a Three hour hold at 1700 deg F

25 deg F an hour to 1650 deg F then a one hour hold at 1650 deg F

Clay body is a grolleg porcelain from Tacoma Clay Art Center.

glaze compositions

Background glaze

Empirical Formula satIron_ZG_Ip7_5 :

K2O        .07
Na2O        .44
Li2O        .2
CaO        .12
MgO        .17

Al2O3        .71
Fe2O3        .1

SiO2        3.13
P2O5        0.04

molecular percent Silica 63%



Inlay Glaze

alexanderBowl_0_Z1Y :

K2O        .09
Na2O        .05
CaO        .70
MgO        .16

Al2O3        .43

SiO2        2.7

molecular percent Silica 65%



Remarks

The background glaze, and inlay glaze belong to different glaze families. The background is a high alumina glaze,
high in alkali metals, containing both iron and phosphorus; the inlay glaze is a high in calcia. The high viscosity
of the inlay glaze is a consequence of its low alkali metal content.

Analogous to the spread of dye poured into water, the components move from high to low concentration across the inlay boundary.
The resulting cross diffusion; the movement of the alkaline earths from inlay into background, and the alkali metals
from background into inlay, creates a design which is only suggested by the original mask.

The contrasting composition of the two glazes creates an interaction region that covers nearly all of the original design
in addition to an even larger region of the background glaze.

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