The effect of lithium on a local reduction Celedon glaze

Replacing the lithium in a celedon glaze with K2O + Na2O transforms a greenish grey celedon glaze to an aqua celedon.

The second glaze has the same mole fraction of alkali metals as the first, the lithium oxide has been replace by K2O + Na2O. glaze.



Glaze celedon_PA_0

The glaze containing lithium

A translucent pale grey-green glaze, full gloss, the translucent results from small bubbles traped beneatht the glaze surface.

full view

full view

bowl is ~4 inches in diameter



Glaze celedon_PA_Z2D

glaze with no lithium.

A translucent pale aqua glaze, full gloss, the translucent results from small bubbles traped beneatht the glaze surface.

full view

full view

bowl is ~4 inches in diameter



oxidation firing to cone 10 in an electric kiln

Firing profiles

Up Fire profile

150 deg F an hour to 250 deg F

400 deg F an hour to 1800 deg F

300 deg F an hour to 2050 deg F

120 deg F an hour to 2310 deg F with a hold of 20 minutes at 2310 deg F

Down Fire Profile

300 deg F an hour to 1750 deg F then a half hour hold at 1750 deg F

300 deg F an hour to 1700 deg F then a Three hour hold at 1700 deg F

25 deg F an hour to 1650 deg F then a one hour hold at 1650 deg F

Clay body is a grolleg porcelain from Tacoma Clay Art Center.

glaze compositions

Empirical Formula glaze celedon_PA_0 :

K2O        .11
Na2O        .15
Li2O        .1
CaO        .49
MgO        .06
ZnO        .09

Al2O3        .4
Fe2O3        .02

SiO2        3.82

molecular percent Silica 72.8%

glaze has 0.2% silicon carbide added for local reduction of iron.



Empirical Formula Glaze celedon_PA_Z2D

K2O        .18
Na2O        .18
CaO        .49
MgO        .06
ZnO        .09

Al2O3        .4
Fe2O3        .013

SiO2        3.82
TiO2       

molecular percent Silica 73%

glaze has 0.2% silicon carbide added for local reduction of iron.



Remarks

The glaze celedon_PA_Z2D also has slightly less Fe2O3 than glaze celedon_PA_0, did that deficit in iron contribute to the change in color?

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