Nickel Colors

This glaze has a micro-crystalline surface layer in a transparent matrix. It contains barium oxide and zinc oxide.
The microcrystalline phase is a deap aqua as a result of the addition of nickel oxide. The glossy matrix is brown.

This glaze is derived by a circuitous route from the glaze number 404 in Emmanuel Cooper book
"The Potters Book of Glaze Recipes".

cooper_404_Z2F_1

full view

inside of bowl:



full view

Outside of bowl:



bowl is ~3 inches in diameter



oxidation firing to cone 10 in an electric kiln

Firing profiles

Up Fire profile

150 deg F an hour to 250 deg F

400 deg F an hour to 1800 deg F

300 deg F an hour to 2050 deg F

120 deg F an hour to 2310 deg F with a hold of 20 minutes at 2310 deg F

Down Fire Profile

300 deg F an hour to 1750 deg F then a half hour hold at 1750 deg F

300 deg F an hour to 1700 deg F then a Three hour hold at 1700 deg F

25 deg F an hour to 1650 deg F then a one hour hold at 1650 deg F

Clay body is a grolleg porcelain from Tacoma Clay Art Center.

glaze compositions

Empirical Formula glaze cooper_404_Z2F_1 :

This glaze has 1.5% Nickel Oxide added

K2O        0.11
Na2O        0.02
CaO        0.01
MgO        0.01
BaO        0.22
ZnO        0.63

Al2O3        0.35

SiO2        2.23

molecular percent Silica 62%



Remarks

The spirit of the original cooper glaze is low alkali metals; this glaze has alkali metals 0.13 essentially the same as the 0.12 of the original
Cooper glaze.

Most of the BaO in the original glaze is replaced by ZnO, and alumina and silica are significantly higher.

This glaze is separated into two distinct phases, a microcrystalline phase which is prominent where the glaze is thickly applied,
and a full gloss transparent matrix which peeks out where the glaze is thin.

The nickel oxide colors the microcrystalline glaze an intense aqua, and the matrix brown.

Note that this glaze has minimal CaO, only that CaO and MgO which are present in all clays and feldspars.
Previous work on glazes colored with nickel oxide has convinced me that CaO promotes gray and brown colors.

The brown matrix shows that nickel oxide can color a glaze brown even if the glaze is low in CaO.

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