Reactions at the interface between two glazes

The interaction at the interface of adjacent glazes.

Several closeups of the interaction region of the two glazes are shown and, for context, a picture of the pot.

The background glaze is longquan_n_song_Z2H_0PSi; the foreground design is glazed with iron_8_R_C10_13PSi.

The background glaze is grey in an oxidation firing as it contains silicon carbide as a local reducing agent.

The design is created by adhering a mask and then applying the main glaze. After drying, the entire pot is coated in wax,
then the mask is removed and the open area filled in with a second glaze.



Close up Images of the interaction region

full view

full view

full view



Image of the piece

full view

bowl with glaze longquan_n_song_Z2H_0PSi and inlay iron_8_R_C10_13PSi

bowl is ~6.5 inches in diameter



oxidation firing to cone 10 in an electric kiln

Firing profiles

Up Fire profile

150 deg F an hour to 250 deg F

400 deg F an hour to 1800 deg F

300 deg F an hour to 2050 deg F

120 deg F an hour to 2310 deg F with a hold of 20 minutes at 2310 deg F

Down Fire Profile

300 deg F an hour to 1750 deg F then a half hour hold at 1750 deg F

300 deg F an hour to 1700 deg F then a Three hour hold at 1700 deg F

25 deg F an hour to 1650 deg F then a one hour hold at 1650 deg F

Clay body is a grolleg porcelain from Tacoma Clay Art Center.

glaze compositions

Background glaze

Empirical Formula longquan_n_song_Z2H_0PSi :

K2O        0.14
Na2O        0.07
CaO        0.58
MgO        0.12
ZnO        0.09

Al2O3        0.54
Fe2O3        0.02

SiO2        3.41

molecular percent Silica 68.6%

0.02% Silicon Carbide added



Inlay Glaze

iron_8_R_C10_13PSi :

K2O        0.11
Na2O        0.45
Li2O        0.25
CaO        0.17
MgO        0.02

Al2O3        0.56
Fe2O3        0.28

SiO2        3.12

molecular percent Silica 63%



Remarks

The background glaze and inlay glaze are from disparate regions in the land of glaze. The background glaze is high in alkaline earths,
particularly calcia; the inlay glaze is a saturated iron glaze high in Alkali metals.
The background glaze is nearly a clear celadon, but it contains more alumina and less alkali metals than
a clear celadon glaze.

The high viscosity of the background glazes is a consequence of the combination of low alkali metals with
relatively high alumina.

Both the alkali metals and iron have diffused from the inlay glaze into the background glaze, but at different rates.
That difference in the rate of flow of the alkalies and iron has generated a range of compositions in the interaction zone, creating the range of
colors and textures seen here.

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