Migrating abutting glazes

The interface of adjacent glazes.

Several closeups of the interaction region of the two glazes are shown and, for context, a picture of the pot.

The background glaze is satIron_ZL_3, the foreground design is glazed with paperWhite_ZV_3_Z2H. paperWhite_ZV_3_Z2H contains cobalt.

The design is created by adhering a mask and then applying the main glaze. After drying, the entire pot is coated in wax,
then the mask is removed and the open area filled in with a second glaze.



Close up Images of the interaction region

full view

full view

full view



Image of the piece

full view

plate with glaze satIron_ZL_3 and inlay glaze paperWhite_ZV_3_Z2H

plate is ~10 inches in diameter



oxidation firing to cone 10 in an electric kiln

Firing profiles

Up Fire profile

150 deg F an hour to 250 deg F

400 deg F an hour to 1800 deg F

300 deg F an hour to 2050 deg F

120 deg F an hour to 2310 deg F with a hold of 20 minutes at 2310 deg F

Down Fire Profile

300 deg F an hour to 1750 deg F then a half hour hold at 1750 deg F

300 deg F an hour to 1700 deg F then a Three hour hold at 1700 deg F

25 deg F an hour to 1650 deg F then a one hour hold at 1650 deg F

Clay body is a grolleg porcelain from Tacoma Clay Art Center.



glaze compositions

background Glaze

satIron_ZL_3:

K2O        0.07
Na2O        0.44
Li2O        0.21
CaO        0.15
MgO        0.13

Al2O3        0.79
Fe2O3        0.1

SiO2        3.30
P2O5        0.05

molecular percent Silica 62.9%



Inlay glaze

Empirical Formula paperWhite_ZV_3_Z2H :

K2O        0.05
Na2O        0.15
Li2O        0.20
CaO        0.02
MgO        0.02
BaO        0.28
SrO        0.28

Al2O3        0.6

SiO2        3.2
TiO2        0.16

molecular percent Silica 64.6%

Added:

1% cobalt carbonate



Remarks

The pale blue shadow framing much of the inlay marks the original position of the design.

There are three distinct rings between the inner region of the inlay glaze and the outer region of background matrix.
Starting at the edge of the inlay, they are characterized as:

opaque pale blue
opaque dark brown
golden brown crystals

The golden brown crystals are found scattered across the background matrix.

The background glaze has CaO, and MgO, of which the inlay has only a trace of either. Additionally, the background
glaze is substantially higher in Fe2O3 and Na2O than the inlay glaze. The inlay on the other hand,
has substantial BaO and SrO, of which the background has none.

Likely the CaO, MgO, Fe2O3 and Na2O diffused from high concentration in the matrix to low concentration in the inlay,
while both BaO and SrO diffused from inlay into background.

Many oxides moving in both directions, each with its own rate of flow would account for the final result of three
distinct rings in the interaction region.

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