Surprising non glaze

This non-glaze is covered in un-popped bubbles. With rather rough handling these bubbles haven't popped. Much gas
must have been generated to have produced that froth of bubbles. Where did it come from, and why are the bubbles so strong?

The glaze, longquan-n-song-tsabar-Z2S, from which this glaze, ru-tsabar-Z2T-0, is derived is semi-matte with variegated orange markings.
If thickly applied longquan-n-song-tsabar-Z2S is glossy, uniform and semi-opaque, a rather insipid milky glass white.

I'd thought to stabilize the matte texture and increase the prominence of the markings with a moderate increase in alumina and silica.
Instead, the result is the bubbled confection seen below.

longquan-n-song-tsabar-Z2S

full view

inside of bowl:



full view

Outside of bowl:



ru-tsabar-Z2T-0

full view

inside of bowl:



full view

Outside of bowl:



bowls are ~3 inches in diameter



oxidation firing to cone 10 in an electric kiln

Firing profiles

Up Fire profile

150 deg F an hour to 250 deg F

400 deg F an hour to 1800 deg F

300 deg F an hour to 2050 deg F

120 deg F an hour to 2310 deg F with a hold of 20 minutes at 2310 deg F

Down Fire Profile

300 deg F an hour to 1750 deg F then a half hour hold at 1750 deg F

300 deg F an hour to 1700 deg F then a Three hour hold at 1700 deg F

25 deg F an hour to 1650 deg F then a one hour hold at 1650 deg F

Clay body is a grolleg porcelain from Tacoma Clay Art Center.

glaze compositions

Empirical Formula glaze longquan-n-song-tsabar-Z2S :

This glaze has 0.2% silicon carbide added for local reduction.

K2O        0.19
Na2O        0.06
CaO        0.62
MgO        0.07
ZnO        0.06

Al2O3        0.56
Fe2O3        0.01

SiO2        2.76

molecular percent Silica 63.6%



Empirical Formula glaze ru-tsabar-Z2T-0 :

This glaze has 0.2% silicon carbide added for local reduction.

K2O        0.16
Na2O        0.07
Li2O        0.06
CaO        0.59
MgO        0.08
ZnO        0.04

Al2O3        0.6
Fe2O3        0.02

SiO2        3.12

molecular percent Silica 65.6%



Remarks

Increasing both alumina and silica while maintaining a constant silica alumina ratio is equivalent to decreasing the basic components
of the glaze, those components in the first column of the seger formula. Here the silica also is increased. The second glaze,
the one with the bubbles, has less flux.

It's as if there are two glazes here, one which melts low and flows, and another which when it starts to melt can't de-gass through the
already melted surface layer.

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