Alkali vs Calcium

Two glazes which differ in the balance of alkali metals and alkaline earths.

The first glaze faux-tsabar-ru-Z2U-0 is higher in alkali metals, the second in alkaline earths.
Some potassium oxide and sodium oxide in the first glaze is replaced with calcium oxide
to get the second glaze.

The glazes

faux-tsabar-ru-Z2U-0

The higher alkali metal glaze:

full view

Inside of bowl:

full view

Outside of bowl:

bowl is ~3 inches in diameter



glaze faux-tsabar-ru-Z2U-1

The higher calcia glaze:

full view

Inside of bowl:

full view

Outside of bowl:

bowl ~3 inches in diameter



oxidation firing to cone 10 in an electric kiln

Firing profiles

Up Fire profile

150 deg F an hour to 250 deg F

400 deg F an hour to 1800 deg F

300 deg F an hour to 2050 deg F

120 deg F an hour to 2310 deg F with a hold of 20 minutes at 2310 deg F

Down Fire Profile

300 deg F an hour to 1750 deg F then a half hour hold at 1750 deg F

300 deg F an hour to 1700 deg F then a Three hour hold at 1700 deg F

25 deg F an hour to 1650 deg F then a one hour hold at 1650 deg F

Clay body is a grolleg porcelain from Tacoma Clay Art Center.



glaze compositions

Empirical Formula faux-tsabar-ru-Z2U-0 :

K2O        0.19
Na2O        0.23
CaO        0.45
MgO        0.13

Al2O3        0.54

SiO2        2.84

molecular percent Silica 65%

Added:

0.5% Copper Carbonate

0.5% silicon carbide for local reduction



Empirical Formula faux-tsabar-ru-Z2U-1 :

K2O        0.15
Na2O        0.13
CaO        0.59
MgO        0.13

Al2O3        0.55

SiO2        2.8

molecular percent Silica 64%

added:

0.5% Copper Carbonate

0.5% silicon carbide for local reduction



Remarks

Both of these glazes are multi-phase assemblages, containing both a full gloss phase and a waxy matte phase.

In the high alkali metal glaze, faux-tsabar-ru-Z2U-0, the full gloss phase dominates, and is purple.

In the high calcia glaze, faux-tsabar-ru-Z2U-1, the waxy matte phase dominates. Additionally, in this glaze,
the glossy phase is mixed aqua and pink, showing it to have a different composition that the glassy phase in
the high alkali metal glaze.

If applied thickly, the high calcia glaze, faux-tsabar-ru-Z2U-1, has interesting marking, yet is crazed.

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