bubble artifacts in glaze

The strange marking found in the surface of this glaze are the residual artifacts of bubbles forming in the glaze
during maturation. These bubbles healed and were reabsorbed by the glaze at a temperature close to the
maximum temperature reached before cooling. A smooth surface remains, though with inhomogeneities in the
surface composition.

The network of rings seen on both the inside and outside of this bowl, mark the location of the now healed bubbles
in the surface.

To me, this pattern looks like the underside of a bubble froth on a transparent surface.

To enhance the circular features I see in the surface, I've played about with photoshop, the results are
the images of the surface features shown. I also show images of the pot.

This glaze was derived from the second glaze shown here:

iron_satIron_Z2T_0

iron_satIron_Z2T_0MAlk has less alkali metals, less silica, and more alumina, so is expectedly
more refractory.



Image of the glaze iron_satIron_Z2T_0_MAlk

full view

inside



full view

outside

bowl is is 3 inches in diameter



Images of the surface modified to make bubble artifacts more visible

This glaze looks nothing like these pictures! These images emphasize the collapsed bubbles,
while severely distorting the glaze.

full view

the entire inside of bowl



full view

an enlarged fraction of the modified image of the inside of bowl



full view

an enlarged fraction of the modified image of the outside of bowl



oxidation firing to cone 10 in an electric kiln

Firing profiles

Up Fire profile

150 deg F an hour to 250 deg F

400 deg F an hour to 1800 deg F

300 deg F an hour to 2050 deg F

120 deg F an hour to 2310 deg F with a hold of 20 minutes at 2310 deg F

Down Fire Profile

300 deg F an hour to 1750 deg F then a half hour hold at 1750 deg F

300 deg F an hour to 1700 deg F then a Three hour hold at 1700 deg F

25 deg F an hour to 1650 deg F then a one hour hold at 1650 deg F

Clay body is a grolleg porcelain from Tacoma Clay Art Center.



glaze compositions

Empirical Formula iron_satIron_Z2T_0_MAlk :

K2O        0.25
Na2O        0.38
CaO        0.26
MgO        0.11

Al2O3        0.71
Fe2O3        0.21

SiO2        3.88
P2O5        0.06

molecular percent Silica 66%



Empirical Formula iron_satIron_Z2T_0 :

K2O        0.23
Na2O        0.44
CaO        0.22
MgO        0.11

Al2O3        0.66
Fe2O3        0.22

SiO2        4.19
P2O5        0.05

molecular percent Silica 68%



Remarks

Bubbles form in a glaze as it matures. As noted above, this glaze, iron_satIron_Z2T_0_MAlk,
expectedly has a higher maturing temperature. A glaze with unhealed bubbles is underfired.
Bubble artifacts could be expected in an almost underfired glaze.

I see a pattern that resembles the edges of bubbles and, as noted above, the existence of healed bubbles
is a plausible assumption. So, I rolled it all together and decided I was seeing bubble residue in a marginally
mature glaze.

The striking difference in color between the inside and outside of the bowl is real, The glaze application
on the inside of the bowl is thicker. This is that rare situation where a thin glaze application of a saturated
iron glaze is more attractive.

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