Migrating abutting glazes

The interface of adjacent glazes.

Several closeups of the interaction region of the two glazes are shown and, for context, a picture of the pot.

The background glaze is hankPaper_Z1R_2C_1; the foreground design is glazed with iron_8_R_C10_13PSi.

The design is created by adhering a mask and then applying the main glaze. After drying, the entire pot is coated in wax,
then the mask is removed and the open area filled in with a second glaze.



Close up Images of the interaction region

full view

full view

full view

full view



Image of the piece

full view

bowl with glaze glaze hankPaper_Z1R_2C_1 and inlay iron_8_R_C10_13PSi

bowl is ~7 inches in diameter



oxidation firing to cone 10 in an electric kiln

Firing profiles

Up Fire profile

150 deg F an hour to 250 deg F

400 deg F an hour to 1800 deg F

300 deg F an hour to 2050 deg F

120 deg F an hour to 2310 deg F with a hold of 20 minutes at 2310 deg F

Down Fire Profile

300 deg F an hour to 1750 deg F then a half hour hold at 1750 deg F

300 deg F an hour to 1700 deg F then a Three hour hold at 1700 deg F

25 deg F an hour to 1650 deg F then a one hour hold at 1650 deg F

Clay body is a grolleg porcelain from Tacoma Clay Art Center.



glaze compositions

Background glaze

Empirical Formula hankPaper_Z1R_2C_1 :

K2O        0.12
Na2O        0.12
Li2O        0.05
CaO        0.14
MgO        0.02
BaO        0.31
SrO        0.24

Al2O3        0.42

SiO2        2.7
TiO2        0.14

molecular percent Silica 63%

Added:

1% Cobalt Carbonate .67% Copper Carbonate



Inlay Glaze

Empirical Formula iron_8_R_C10_13PSi :

K2O        0.11
Na2O        0.45
Li2O        0.25
CaO        0.17
MgO        0.02

Al2O3        0.56
Fe2O3        0.28

SiO2        3.12

molecular percent Silica 63%



Remarks

The inlay glaze is higher in alkali metals, silica and alumina.

Silica and alkali metals migrate from the inlay into the matrix, while alkaline earths migrate in the opposite
direction, from the matrix into the inlay. In both cases, as ink spreads in water, so migration is against
the compositional gradient, from high concentration to low concentration.

Most of the inlay has been consumed by the mongrel interface composition. The inlay mask had been continuous,
connecting the current dark glossy pools. The brown/yellow areas cover regions through which
the inlay had once passed.

Radially arrayed needle crystals have grown in the interaction region where the two glazes have grown together.

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