Less Silica

A small decrease in silica produced a large difference in crystal growth in two tenmoku glazes.

The Glaze iron_satIron_Z2W_Z2Z was derived from the glaze iron_satIron_Z2W_Z2Y_0 by a decrease
in silica; there were slight shifts in other oxides to accommodate this reduction in silica.

Images are shown of the precursor glaze, iron_satIron_Z2W_Z2Y_0 with higher silica, and its derived
glaze iron_satIron_Z2W_Z2Z_0.



Image of the precursor glaze, iron_satIron_Z2W_Z2Y_0

This is the glaze with higher silica.

full view

inside

full view

outside

bowl is is 3 inches in diameter



Image of the glaze iron_satIron_Z2W_Z2Z_0

The derived glaze, the glaze with lower silica.

full view

inside

full view

outside

bowl is is 3 inches in diameter



oxidation firing to cone 10 in an electric kiln

Firing profiles

Up Fire profile

150 deg F an hour to 250 deg F

400 deg F an hour to 1800 deg F

300 deg F an hour to 2050 deg F

120 deg F an hour to 2310 deg F with a hold of 20 minutes at 2310 deg F

Down Fire Profile

300 deg F an hour to 1750 deg F then a half hour hold at 1750 deg F

300 deg F an hour to 1700 deg F then a Three hour hold at 1700 deg F

25 deg F an hour to 1650 deg F then a one hour hold at 1650 deg F

Clay body is a grolleg porcelain from Tacoma Clay Art Center.



glaze compositions

Empirical Formula iron_satIron_Z2W_Z2Y_0 :

K2O        0.11
Na2O        0.48
Li2O        0.28
CaO        0.02
MgO        0.11

Al2O3        0.66
Fe2O3        0.24

SiO2        3.74

molecular percent Silica 66%



Empirical Formula iron_satIron_Z2W_Z2Z_0 :

K2O        0.10
Na2O        0.50
Li2O        0.26
CaO        0.03
MgO        0.11

Al2O3        0.66
Fe2O3        0.22

SiO2        3.4

molecular percent Silica 64%



Remarks

Both glazes are comprised of a glossy black matrix with a dusting of coppery colored micro-crystals. In the glaze with
the reduced silica, the density of the micro-crystals is significantly greater.

Presumably, the iron is more soluble in the higher silica glaze, so during the cooling less iron precipitates
to form the micro-crystals.

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