Less Silica

A small decrease in silica produced different crystals in an altered matrix, this in a high alkali metal glaze containing BaO.

The glaze alk_179_Z30_0 was derived from the glaze alk_179_1_Z2Z by a decrease in silica;
after normalization of the recipe to 100, there were slight shifts in other oxides to accommodate this reduction in silica.

Images are shown of the precursor glaze, alk_179_1_Z2Z with higher silica, and its derived
glaze alk_179_Z30_0.



Image of the precursor glaze, alk_179_1_Z2Z

This is the glaze with higher silica.

full view

inside

full view

outside

bowl is is 3 inches in diameter



Image of the glaze alk_179_Z30_0

The derived glaze, the glaze with lower silica.

full view

inside

full view

outside

bowl is is 3 inches in diameter



oxidation firing to cone 10 in an electric kiln

Firing profiles

Up Fire profile

150 deg F an hour to 250 deg F

400 deg F an hour to 1800 deg F

300 deg F an hour to 2050 deg F

120 deg F an hour to 2310 deg F with a hold of 20 minutes at 2310 deg F

Down Fire Profile

300 deg F an hour to 1750 deg F then a half hour hold at 1750 deg F

300 deg F an hour to 1700 deg F then a Three hour hold at 1700 deg F

25 deg F an hour to 1650 deg F then a one hour hold at 1650 deg F

Clay body is a grolleg porcelain from Tacoma Clay Art Center.



glaze compositions

Empirical Formula alk_179_1_Z2Z :

K2O        0.16
Na2O        0.19
Li2O        0.25
CaO        0.02
MgO        0.27
BaO        0.11

Al2O3        0.52
Fe2O3        0.05

SiO2        3.17
TiO2        0.18

molecular percent Silica 64%



Empirical Formula alk_179_Z30_0 :

K2O        0.16
Na2O        0.19
Li2O        0.26
CaO        0.02
MgO        0.27
BaO        0.10

Al2O3        0.52
Fe2O3        0.04

SiO2        2.45
TiO2        0.16

molecular percent Silica 59%



Remarks

Both glazes are comprised of a glossy brown matrix with variegated yellow-colored micro-crystal clusters. In the glaze with
the reduced silica, the crystal clusters are significanlty larger, and the matrix has opalescent markings.

The lower silica glaze has considerably lower viscosity that its higher silica parent; it dripped
onto the kiln shelf and allowed the crystal clusters to grow larger.

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