Higher Calcium

A small increase in calcium produced a profusion of crystals, this in a high alkali metal glaze.
The crystals are acicular, as they were in the precursor glaze, yet they have changed, being now matte.

The glaze satIron_Alex_Z30 was derived from the glaze satIron_P_Alex by a shift toward the right in a line blend
of the two glazes satIron_ZG_Ip7_5 and alexanderBowl_0_Z1Y. The result was a glaze slightly higher in CaO,
and correspondingly lower in alkali metals.

Images are shown of the precursor glaze, satIron_P_Alex with lower CaO, and its derived
glaze satIron_Alex_Z30.



Image of the precursor glaze, satIron_P_Alex

This is the glaze with lower CaO.

full view

inside

full view

outside

bowl is is 3 inches in diameter



Image of the glaze satIron_Alex_Z30

The derived glaze, the glaze with higher CaO.

full view

inside

full view

outside

bowl is is 3 inches in diameter



oxidation firing to cone 10 in an electric kiln

Firing profiles

Up Fire profile

150 deg F an hour to 250 deg F

400 deg F an hour to 1800 deg F

300 deg F an hour to 2050 deg F

120 deg F an hour to 2310 deg F with a hold of 20 minutes at 2310 deg F

Down Fire Profile

300 deg F an hour to 1750 deg F then a half hour hold at 1750 deg F

300 deg F an hour to 1700 deg F then a Three hour hold at 1700 deg F

25 deg F an hour to 1650 deg F then a one hour hold at 1650 deg F

Clay body is a grolleg porcelain from Tacoma Clay Art Center.



glaze compositions

Empirical Formula satIron_P_Alex :

Precursor glaze with lower CaO.

K2O        0.08
Na2O        0.36
Li2O        0.16
CaO        0.23
MgO        0.17

Al2O3        0.65
Fe2O3        0.09

SiO2        3
P2O5        0.03

molecular percent Silica 63%



Empirical Formula satIron_Alex_Z30 :

Derived glaze with higher CaO.

K2O        0.08
Na2O        0.33
Li2O        0.16
CaO        0.26
MgO        0.17

Al2O3        0.64
Fe2O3       0.07

SiO2        3
P2O5        0.02

molecular percent Silica 63%



Empirical Formula satIron_ZG_Ip7_5 Left end of line blend:

K2O        .07
Na2O        .44
Li2O        .2
CaO        .12
MgO        .17

Al2O3        .71
Fe2O3        .1

SiO2        3.13
P2O5        0.04

molecular percent Silica 63%



Empirical Formula alexanderBowl_0_Z1Y Right end of line blend :

K2O        .09
Na2O        .05
CaO        .70
MgO        .16

Al2O3        .43

SiO2        2.7

molecular percent Silica 65%



Remarks

The glaze satIron_P_Alex has some crystals in a glossy matrix, less than 50% surface coverage; in contrast
the glaze satIron_Alex_Z30 has nearly dense surface crystals, with only a bit of matrix peeking through.

The glaze satIron_Alex_Z30 has higher CaO and as a result an alkali metal: alkaline earth ratio of 1.3:1;
lower than that of satIron_P_Alex, which is 1.5:1.

satIron_Alex_Z30 with lower alkali metals, is less fluid, didn't drip, and no shelf cleaning required.

In this case, more crystals grow in the higher viscosity, less fluid glaze with lower alkali metals.

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