Reactions between glazes which abut and overlap

The interface of adjacent glazes from divergent glaze families.

The matrix glaze is a high iron glaze that is high in alkali metals; the inlay glaze by contrast,
is high in alkaline earths.

Several closeups of the interaction region of the two glazes are shown and, for context, a picture of the pot.

The background glaze is iron_satIron_Z2V_0; the foreground design is glazed with alexanderBowl_0_Z1Y.

The design is created by adhering a mask and then applying the main glaze. After drying, the mask is removed
and the open area filled in with a second glaze. As the step of waxing the pot before removal of the mask is eliminated,
there is some overlap of the inlay glaze and matrix glaze. The maximum width of the mask is ~ 3/4 inch, the maximum overlap
of the two glazes, ~1/16 inch. The filling is done with an ear syringe which emits a stream of approximately 1/8th
inch diameter.



Close up Images of the interaction region

full view

full view

full view

full view



Image of the piece

full view

bowl with glaze iron_satIron_Z2V_0 and inlay alexanderBowl_0_Z1Y

bowl is 8 inches in diameter



oxidation firing to cone 10 in an electric kiln

Firing profiles

Up Fire profile

150 deg F an hour to 250 deg F

400 deg F an hour to 1800 deg F

300 deg F an hour to 2050 deg F

120 deg F an hour to 2315 deg F with a hold of 20 minutes at 2310 deg F

Down Fire Profile

300 deg F an hour to 1750 deg F then a half hour hold at 1750 deg F

300 deg F an hour to 1700 deg F then a Three hour hold at 1700 deg F

25 deg F an hour to 1650 deg F then a one hour hold at 1650 deg F

Clay body is a grolleg porcelain from Tacoma Clay Art Center.



glaze compositions

Background glaze

Empirical Formula iron_satIron_Z2V_0 :

K2O        0.19
Na2O        0.3
Li2O        0.27
CaO        0.18
MgO        0.06

Al2O3        0.55
Fe2O3        0.20

SiO2        3.17
P2O5        0.04

molecular percent Silica 63.8%



Inlay Glaze

Empirical Formula alexanderBowl_0_Z1Y :

K2O        0.09
Na2O        0.05
CaO        0.70
MgO        0.16

Al2O3        0.43
Fe2O3        0.02

SiO2        2.67

molecular percent Silica 65%

Added:

1% Cobalt Carbonate 0.34% Chrome Oxide



Remarks

The viscous inlay glaze is higher in alkaline earths, while the more fluid background glaze is high
in alkali metals.

There are patches of a drippy black liquid that formed within the matrix glaze, though only at the edge of the inlay glaze.
On a vertical wall, it flowed mightily; like a river, it poured through everything and changed the design greatly.
Like what happens to a watercolor painting on an easel if you get it too wet.

Small acicular crystals formed within the glossy black phase.

The close-up images have been heavily edited to show the structure of the crystals forming in the interaction region,
with the result that the colors are overly bright. The image of the bowl has accurate colors. The matrix glaze is
covered in metallic micro-crystals and reflects like a mirror.

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