Reactions between glazes which abut and overlap

The interface of adjacent glazes from divergent glaze families.

The matrix glaze is a high iron glaze that is high in alkali metals, alumina and silica; the inlay glaze by contrast,
is low in iron and high in alkaline earths.

Several closeups of the interaction region of the two glazes are shown and, for context, a picture of the pot.

The background glaze is iron_satIron_Z2W_Z2Z_0; the foreground design is glazed with alexanderBowl_0_Z1Y.

The design is created by adhering a mask and then applying the main glaze. After drying, the mask is removed
and the open area filled in with a second glaze. As the step of waxing the pot before removal of the mask is eliminated,
there is some overlap of the inlay glaze and matrix glaze. The maximum width of the mask is ~ 3/4 inch, the maximum overlap
of the two glazes pre-firing, ~1/16 inch. The filling is done with an ear syringe which emits a stream of
approximately 1/8th inch diameter.



Close up Images of the interaction region

full view

full view

full view

full view



Image of the piece

full view

bowl with glaze iron_satIron_Z22W_Z2Z_0 and inlay alexanderBowl_0_Z1Y

bowl is 8 inches in diameter



oxidation firing to cone 10 in an electric kiln

Firing profiles

Up Fire profile

150 deg F an hour to 250 deg F

400 deg F an hour to 1800 deg F

300 deg F an hour to 2050 deg F

120 deg F an hour to 2310 deg F with a hold of 20 minutes at 2310 deg F

Down Fire Profile

300 deg F an hour to 1750 deg F then a half hour hold at 1750 deg F

300 deg F an hour to 1700 deg F then a Three hour hold at 1700 deg F

25 deg F an hour to 1650 deg F then a one hour hold at 1650 deg F

Clay body is a grolleg porcelain from Tacoma Clay Art Center.



glaze compositions

Background glaze

Empirical Formula iron_satIron_Z2W_Z2Z_0 :

K2O        0.10
Na2O        0.50
Li2O        0.26
CaO        0.03
MgO        0.11

Al2O3        0.66
Fe2O3        0.22

SiO2        3.4

molecular percent Silica 64.3%



Inlay Glaze

Empirical Formula alexanderBowl_0_Z1Y :

K2O        0.09
Na2O        0.05
CaO        0.70
MgO        0.16

Al2O3        0.43
Fe2O3        0.02

SiO2        2.67

molecular percent Silica 65%

Added:

1% Cobalt Carbonate 0.34% Chrome Oxide



Remarks

The viscous inlay glaze is higher in alkaline earths, while the more fluid background glaze is high
in alkali metals, iron, silica and alumina.

The background glaze is an exceedingly fluid aventurine-type tenmoku glaze. It is sufficiently more fluid than the
inlay glaze that it occasionally flowed through it as ocean waves through wet sand; substantially transforming the inlay glaze.
The inlay glaze morphed from its more usual waxy matte textured pale yellow into a maze of many-colored streaks of yellows,
greens and shades of brown.

Small acicular crystals formed in the interface between the matrix and inlay glazes.

The close-up images have been edited to show the structure of the crystals forming in the interaction region,
with the result that the colors are shifted. The image of the bowl has accurate colors. The matrix glaze is
covered in metallic micro-crystals and reflects like a mirror.

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