Migrating disparate abutting glazes

The interface of adjacent glazes from distinct glaze families. The matrix glaze and inlay glaze overlap
by no more than an eighth of an inch before firing, with no overlap whatever for large parts of the design.
The original mask for the inlay was a wiggly curved line that enclosed an ovoid. A scribble,
and nowhere more than half an inch across.

The flowing of the matrix glaze, together with cross diffusion between the two glazes, and crystal growth
in both glazes, nearly filled the entire region delimited by the individual lines of the masks.

The matrix glaze is a high iron glaze that is high in alkali metals and alumina, yet relatively
low in silica, with a silica alumina ratio of 4.4. The inlay glaze by contrast, is high in alkaline earths,
lower in alumina.

Several closeups of the interaction region of the two glazes are shown and, for context, a picture of the pot.

The background glaze is satIron_ZG_Ip7_5, the foreground design is glazed with alexanderBowl_0_Z1Y.

The same background and foreground glaze, with a substantially thinner application of background glaze:

is shown.

Greater glaze thickness resulted in more and larger crystal formation in the matrix glaze.

The design is created by adhering a mask and then applying the main glaze. After drying, the mask is removed
and the open area filled in with a second glaze, using a bulb syringe.



Close up Images of the interaction region

full view

full view

full view

full view



Image of the piece

full view

bowl with glaze satIron_ZG_Ip7_5 and inlay alexanderBowl_0_Z1Y

bowl is ~9 inches in diameter



oxidation firing to cone 10 in an electric kiln

Firing profiles

Up Fire profile

150 deg F an hour to 250 deg F

400 deg F an hour to 1800 deg F

300 deg F an hour to 2050 deg F

120 deg F an hour to 2310 deg F with a hold of 20 minutes at 2310 deg F

Down Fire Profile

300 deg F an hour to 1750 deg F then a half hour hold at 1750 deg F

300 deg F an hour to 1700 deg F then a Three hour hold at 1700 deg F

25 deg F an hour to 1650 deg F then a one hour hold at 1650 deg F

Clay body is a grolleg porcelain from Tacoma Clay Art Center.



glaze compositions

Background glaze

Empirical Formula satIron_ZG_Ip7_5 :

K2O        .07
Na2O        .44
Li2O        .2
CaO        .12
MgO        .17

Al2O3        .71
Fe2O3        .1

SiO2        3.13
P2O5        0.04

molecular percent Silica 63%



Inlay Glaze

alexanderBowl_0_Z1Y :

K2O        .09
Na2O        .05
CaO        .70
MgO        .16

Al2O3        .43

SiO2        2.7

molecular percent Silica 65%

Added:

1% Cobalt Carbonate .67% Copper Carbonate



Remarks

The background glaze is an immensely fluid glaze; it might be seen as a celadon with high iron and low silica.
Micro-crystals appear in this glaze if applied thickly. Its low silica encourages phase separation in the glaze.
The migration of additional CaO and MgO from the inlay glaze make micro-crystal formation more certain,
and as seen here, some of those micro-crystals are nearly 3/8 inch in diameter.

As sugar poured into tea spreads by diffusion into the entire cup, the higher concentration of CaO
in the inlay glaze will migrate into the matrix.

Most of the increase in area covered by the inlay is attributable to crystal growth in the matrix (background) glaze.

The mask for the inlay is a simple wiggly line. After firing, a large part of the area encircled by
the line is a mixture of inlay glaze, matrix glaze, and crystals growing in the matrix.

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