unrelated glazes at a vertical interface

The interactions at a vertical interface between glazes with a different balance of oxides in the seger formula,
thus different phase structure.

The matrix (i.e. background) glaze and inlay glaze overlap by no more than an eighth of an inch before firing,
with no overlap whatever for large parts of the design. The original mask for the inlay was a curved line,
nowhere more than half an inch thick.

The matrix glaze is high in iron, alumina and alkali metals. The inlay glaze, by contrast,
is higher in alkaline earths containing both Barium and Strontium.

Similar artifacts are seen here in the interaction between an unrelated pair of glazes, though also a saturated iron glaze
and a high alkaline earth glaze. Particularly note the occurance of discrete acicular crystals on a glossy black background.

Several closeups of the interaction region of the two glazes are shown and, for context, a picture of the pot.

The background glaze is iron_satIron_Z2W_Z2Z_0, the inlay design is glazed with hankPaper_Z1R_2C_1.

A thick glaze application resulted in large crystals forming in the matrix glaze.

The design is created by adhering a mask and then applying the main glaze. After drying, the mask is removed
and the open area filled in with a second glaze, using a bulb syringe.



Close up Images of the interaction region

full view

full view

full view

full view



Image of the piece

full view

bowl with glaze iron_satIron_Z2W_Z2Z_0 and hankPaper_Z1R_2C_1

bowl is ~9 inches in diameter



oxidation firing to cone 10 in an electric kiln

Firing profiles

Up Fire profile

150 deg F an hour to 250 deg F

400 deg F an hour to 1800 deg F

300 deg F an hour to 2050 deg F

120 deg F an hour to 2310 deg F with a hold of 20 minutes at 2310 deg F

Down Fire Profile

300 deg F an hour to 1750 deg F then a half hour hold at 1750 deg F

300 deg F an hour to 1700 deg F then a Three hour hold at 1700 deg F

25 deg F an hour to 1650 deg F then a one hour hold at 1650 deg F

Clay body is a grolleg porcelain from Tacoma Clay Art Center.



glaze compositions

Background glaze

Empirical Formula iron_satIron_Z2W_Z2Z_0 :

K2O        0.10
Na2O        0.50
Li2O        0.26
CaO        0.03
MgO        0.11

Al2O3        0.66
Fe2O3        0.22

SiO2        3.4

molecular percent Silica 64.3%



Inlay Glaze

Empirical Formula hankPaper_Z1R_2C_1 :

K2O        0.12
Na2O        0.12
Li2O        0.05
CaO        0.14
MgO        0.02
BaO        0.31
SrO        0.24

Al2O3        0.42

SiO2        2.7
TiO2        0.14

molecular percent Silica 63%

Added:

1% Cobalt Carbonate .67% Copper Carbonate



Remarks

Metallic micro-crystals appear in this glaze if applied thickly. Here we see acicular crystals growing
in the interfacial region distinct from its native metallic micro-crystals.

milk spreads by diffusion into the cup of coffee, the higher concentration of alkaline earths and titanium
migrate from the inlay glaze into the matrix, seeding additional phases in the matrix glaze.

Here in the matrix glaze, we see an enhanced non-crystalline phase, a full gloss glassy black phase
of which only hints were otherwise seen.

With the same background glaze and a different inlay glaze alexanderBowl_Z1Y_0
the glossy black phase is minimally present.

Most of the increase in area covered by the inlay is attributable to crystal growth in the matrix glaze,
and dissolution of the matrix glaze resulting from diffusion of inlay glaze into the matrix.

The mask for the inlay is a simple wiggly line. After firing, the inlay is considerably broadened.

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