A tea dust glaze with increased alumina

A tea dust glaze with increased alumina becomes a tenmoku glaze with oil spots.

The glaze iron_DG3_PAl is a descendant of the tea dust glaze seen here .

The tenmoku glaze iron_DG3_PAl has substantially higher alumina than satIron_Z1D_G_3 seen above, while
most of the other oxides in its empirical formula are virtually identical. The small amount of BaO in satIron_Z1D_G_3 is
replaced by MgO.



Bowl with glaze iron_DG3_PAl

full view

inside



full view

outside

bowl is ~ 4 inches in diameter



oxidation firing to cone 10 in an electric kiln

Firing profiles

Up Fire profile

150 deg F an hour to 250 deg F

400 deg F an hour to 2050 deg F

120 deg F an hour to 2250 deg F

60 deg F an hour to 2310 deg F with a hold of 20 minutes at 2310 deg F

Down Fire Profile

300 deg F an hour to 1750 deg F then a half hour hold at 1750 deg F

300 deg F an hour to 1700 deg F then a Three hour hold at 1700 deg F

25 deg F an hour to 1650 deg F then a one hour hold at 1650 deg F

Clay body is a grolleg porcelain from Tacoma Clay Art Center.



glaze compositions

Empirical Formula iron_DG_3_PAl :

K2O        0.27
Na2O        0.27
Li2O        0.29
CaO        0.11
MgO        0.06

Al2O3        0.76
Fe2O3        0.22

SiO2        3.8

molecular percent Silica 65.8%



For comparison the empirical formula of the tea dust glaze:

Empirical Formula satIron_Z1D_G_3 :

K2O        0.27
Na2O        0.27
Li2O        0.28
CaO        0.11
MgO        0.01
BaO        0.06

Al2O3        0.61
Fe2O3        0.21

SiO2        3.8

molecular percent Silica 67.7%



Remarks

The discrete crystals that grow in satIron_Z1D_G_3 are sufficiently small, that a slight increase in alumina
is enough to inhibit their growth altogether.

The iron that is a component of the crystals in the tea dust glaze satIron_Z1D_G_3 remains in the
glaze matrix in the glaze iron_DG3_PAl, resulting in a darker nearly black color. The surface microcrystals that
occasionally coalesce to form nascent oil drops are impeded in size by the viscosity of the higher alumina glaze.

In the more viscous glaze, movement of oxides is slower and crystal growth size is limited by the amount of movement
possible before freezing sets in at the glass transition.

I don't think the replacement of a small amount of BaO with MgO had a significant effect on this glaze.

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