Shifting Edges

A descendant of the glaze seen here .

The glaze shown in this note, iron_Alex_1, is derived from iron_Alex_0. In its empirical formula,
some alkali metals are replaced by CaO, and it has less alumina.

Several small changes combine to generate something which is seemingly unrelated to its source. iron_Alex_1
is a fluid micro-crystalline matte glaze. The only remaining resemblance to its ancestry would be the occurrence of
a multiplicity of distinct intertwined, yet cleanly delineated colors seen on its surface. The sharp boundaries
between the various colors suggests that there are several distinct micro-crystals on this surface.



Image of the glaze iron_Alex_1

full view

inside



full view

outside

bowl is ~ 4 inches in diameter.



oxidation firing to cone 10 in an electric kiln

Firing profiles

Up Fire profile

150 deg F an hour to 250 deg F

400 deg F an hour to 1800 deg F

300 deg F an hour to 2050 deg F

120 deg F an hour to 2310 deg F with a hold of 20 minutes at 2310 deg F

Down Fire Profile

300 deg F an hour to 1750 deg F then a half hour hold at 1750 deg F

300 deg F an hour to 1700 deg F then a Three hour hold at 1700 deg F

25 deg F an hour to 1650 deg F then a one hour hold at 1650 deg F

Clay body is a grolleg porcelain from Tacoma Clay Art Center.



glaze compositions

Empirical Formula iron_Alex_1 :

K2O        0.07
Na2O        0.33
Li2O        0.12
CaO        0.38
MgO        0.10

Al2O3        0.53
Fe2O3        0.15

SiO2        2.97
P2O5        0.02

molecular percent Silica 63.5%



For reference the parent glaze:

Empirical Formula iron_Alex_0 :

K2O        0.08
Na2O        0.37
Li2O        0.14
CaO        0.32
MgO        0.09

Al2O3        0.57
Fe2O3        0.15

SiO2        3.0
P2O5        0.03

molecular percent Silica 63%



Remarks

iron_Alex_1 with lower alumina, but nearly the same silica has a higher silica:alumina ratio, which one might
expect to generate a glossier glaze. Conversely the lower alkali metals would be expected to give a more matte glaze,
which is what occurred. Lower alkali metals trumped higher alumina:silica ratio.

iron_Alex_1 shows its fluidity by the roll of glaze at its foot.

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