Glaze From a Line Blend

A tile in a line blend between two disparate glazes shows a fascinatingly textured effect, but only where the glaze is thin.

The glaze with the composition of that tile is reminiscent of the desired texture, a slight modification gets even closer.

The target tile, #4 from the line blend with left end glaze longquan_n_song_Z2H_0PSi, and right end glaze iron_8_R_C10_13PSi
is comprised of two parts of longquan_n_song_Z2H_0PSi and three parts iron_8_R_C10_13PSi.
I write that as:

0.4 longquan_n_song_Z2H_0PSi + 0.6 iron_8_R_C10_13PSi

and name it longquan_iron_2_3, and its modification longquan_iron_2_3_MZn, with less ZnO and altered alkali metals.

I show images of the two ends of the line blend, the target tile, with its two next neighbor tiles, and the two resulting glazes,
longquan_iron_2_3, and longquan_iron_2_3_MZn.



The ends of the line blend

The Left end glaze is longquan_n_song_Z2H_0PSi, the Right end glaze is iron_8_R_C10_13PSi



the target tile, tile 4, and its two neighbors, tiles 3 and 5



The glaze with composition that of the target tile, tile 4.

Image of the glaze longquan_iron_2_3

full view

inside



full view

outside

bowl is ~ 4 inches in diameter.



The glaze longquan_iron_2_3 without ZnO, and altered alkali metal balance.

Image of the glaze longquan_iron_2_3_MZn

full view

inside



full view

outside

bowl is ~ 4 inches in diameter.





oxidation firing to cone 10 in an electric kiln

Firing profiles

Up Fire profile

150 deg F an hour to 250 deg F

400 deg F an hour to 1800 deg F

300 deg F an hour to 2050 deg F

120 deg F an hour to 2310 deg F with a hold of 20 minutes at 2310 deg F

Down Fire Profile

300 deg F an hour to 1750 deg F then a half hour hold at 1750 deg F

300 deg F an hour to 1700 deg F then a Three hour hold at 1700 deg F

25 deg F an hour to 1650 deg F then a one hour hold at 1650 deg F

Clay body is a grolleg porcelain from Tacoma Clay Art Center.



glaze compositions

Left end glaze

Empirical Formula longquan_n_song_Z2H_0PSi :

K2O        0.14
Na2O        0.07
CaO        0.58
MgO        0.12
ZnO        0.09

Al2O3        0.54
Fe2O3        0.02

SiO2        3.41

molecular percent Silica 68.6%

added .2% SiC



Right end glaze

Empirical Formula iron_8_R_C10_13PSi :

K2O        0.11
Na2O        0.45
Li2O        0.25
CaO        0.17
MgO        0.02

Al2O3        0.56
Fe2O3        0.28

SiO2        3.12

molecular percent Silica 63%



Target tile glaze

Empirical Formula longquan_iron_2_3 :

K2O        0.12
Na2O        0.30
Li2O        0.15
CaO        0.33
MgO        0.06
ZnO        0.04

Al2O3        0.55
Fe2O3        0.17

SiO2        3.2

molecular percent Silica 65.2%



Modified Target tile glaze

Empirical Formula longquan_iron_2_3_MZn :

K2O        0.22
Na2O        0.21
Li2O        0.15
CaO        0.34
MgO        0.08

Al2O3        0.56
Fe2O3        0.18

SiO2        3.1

molecular percent Silica 63.7%



Remarks

Only the thin outer edge of tile 4 shows the multiple colored matte crystals, where thicker, there remains only a
full gloss black glaze. This is also seen in the glaze with that tiles composition, longquan_iron_2_3.

Removing that small bit of Zinc from longquan_iron_2_3 will increase its viscosity, which most likely shifts
the ease with which precipitates form in the glaze. The alkali metals were shifted to a more equal distribution.
Replacing Na2O with K2O likely also increases viscosity.

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