Shifting Edges

The glaze longquan-iron-shino produces an opaque coppery matte surface with black highlights, and a metallic sheen if thin.

The glaze longquan-iron-shino-PAlSi is derived from it by increasing the alumina and silica with nearly the same
silica alumina ratio.

The ratio of alkali metals to alkaline earths in lonquan-iron-shino-PAlSi also increased slightly,
so it might seem that really all that happened is that some CaO was replaced by Alkali metals, but, that change
does not account for the entirety of the increase in Alumina.

The result in a translucent, near black tenmoku with a lustrous iridescent surface film.



Image of the glaze longquan-iron-shino

full view

inside



full view

outside

bowl is ~ 4 inches in diameter.



Image of the glaze longquan-iron-shino-PAlSi

full view

inside



full view

outside

bowl is ~ 4 inches in diameter.



oxidation firing to cone 10 in an electric kiln

Firing profiles

Up Fire profile

150 deg F an hour to 250 deg F

400 deg F an hour to 1800 deg F

300 deg F an hour to 2050 deg F

120 deg F an hour to 2310 deg F with a hold of 20 minutes at 2310 deg F

Down Fire Profile

300 deg F an hour to 1750 deg F then a half hour hold at 1750 deg F

300 deg F an hour to 1700 deg F then a Three hour hold at 1700 deg F

25 deg F an hour to 1650 deg F then a one hour hold at 1650 deg F

Clay body is a grolleg porcelain from Tacoma Clay Art Center.



glaze compositions

Empirical Formula longquan-iron-shino :

K2O        0.21
Na2O       0.31
Li2O       0.19
CaO        0.24
MgO        0.05

Al2O3      0.81
Fe2O3      0.12

SiO2       3.56

molecular percent Silica 64.7%



Empirical Formula longquan-iron-shino-PAlSi :

K2O        0.22
Na2O       0.32
Li2O       0.21
CaO        0.21
MgO        0.04

Al2O3      0.89
Fe2O3      0.13

SiO2       3.93

molecular percent Silica 66.01%



Remarks

longquan-iron-shino-PAlSi is a less viscous glaze than longqun-iron-shino, but only slightly so. The increased alkali metals
have more influence on the viscosity of this glaze than higher Alumina and higher silica.

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