Reacting glazes at a vertical interface

Glazes interacting at a vertical interface.

The matrix (i.e. background) glaze and inlay glaze do not overlap before firing.
The original mask for the inlay was a simple curved line, nowhere more than three eights of an inch thick.

The matrix glaze is high in alkali metals, which results in a low viscosity, fluid glaze.
The inlay glaze is high in alkaline earths and has higher viscosity than the matrix glaze. The inlay glaze is
lower in alumina and silica than the matrix glaze, which increases the fluidity of the mixture
in the interaction region. That increased fluidity encourages crystal growth. This is seen in the line of acicular
crystals growing at the edge of the inlay. These seem to be the same crystals as grow in the
matrix glaze.

The result of the high fluidity of the matrix is a greatly increased flow in the inlay, broadening
the interaction region. The result is that the general form of the inlay together with the interaction region
is only minimally related to the original masks.

Several closeups of the interaction region of the two glazes are shown and, for context, a picture of the pot.

The background glaze is iron_Alex_0_Z36, the inlay design is glazed with alexanderBowl_0_Z1Y.

The design is created by adhering a mask and then applying the main glaze. After drying, the mask is removed
and the open area filled in with a second glaze, using a bulb syringe with a needle applicator.



Close up Images of the interaction region

full view

full view

full view

full view --



Image of the piece

full view

mug with glaze iron_Alex_0_Z36 and inlay glaze alexanderBowl_0_Z1Y.

mug is ~4.5 inches in high



oxidation firing to cone 10 in an electric kiln

Firing profiles

Up Fire profile

150 deg F an hour to 250 deg F

400 deg F an hour to 1800 deg F

300 deg F an hour to 2050 deg F

120 deg F an hour to 2310 deg F with a hold of 20 minutes at 2310 deg F

Down Fire Profile

300 deg F an hour to 1750 deg F then a half hour hold at 1750 deg F

300 deg F an hour to 1700 deg F then a Three hour hold at 1700 deg F

25 deg F an hour to 1650 deg F then a one hour hold at 1650 deg F

Clay body is a grolleg porcelain from Tacoma Clay Art Center.



glaze compositions

Background glaze

Empirical Formula iron_Alex_0_Z36 :

K2O        0.08
Na2O       0.38
Li2O       0.15
CaO        0.29
MgO        0.10

Al2O3      0.60
Fe2O3      0.16

SiO2       3.24
P2O5       0.03

molecular percent Silica 64.6%



Inlay Glaze

Empirical Formula alexanderBowl_0_Z1Y:

K2O        0.09
Na2O       0.05
CaO        0.70
MgO        0.16
BaO       

Al2O3      0.43
Fe2O3      0.02

SiO2       2.67

molecular percent Silica 64.7%



Remarks

For these two fluid glazes, the driving force for interaction is the high mobility of the matrix glaze
together with the difference in composition of the two glazes. The inlay glaze has higher alkaline earths, and lower
alumina and silica.

The extra mass of inlay glaze added to the generous supply of background glaze resulted in a substantial flow at
the bottom of the pot. The pot stuck to the kiln shelf.

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