Reacting glazes at a vertical interface

Glazes interacting at a vertical interface.

The matrix (i.e. background) glaze and inlay glaze do not overlap before firing.
The original mask for the inlay was a simple curved line.

The matrix glaze is substantially higher in Alumina and silica. It contains distinct phases, some more
mobile than others. The result of this non-uniformity of the matrix glaze is that the uniformly viscous inlay
glaze cuts through the liquid parts of the matrix, and is impeded by the rigid components
of the matrix glaze, giving the observed zig-zag pattern of the inlay.

There is diffusion of the higher alkali metals of the matrix glaze into the lower alkali metal inlay glaze;
as seen in the halo of dark brown framing the inlay, and in the yellowish shading of the thinner parts of
an otherwise ivory inlay glaze.

The dark streaks seen above the inlay result from the viscous phase of the matrix glaze pushing down on the
inlay glaze. There are streaks rather than an even line because the solid, boulder-like phase of the matrix
glaze stays put, while the fluid portion flows around the solid pieces and pushes the inlay glaze before
it in the same way a flash flood leaves boulders behind while washing away the soft sand.

Several closeups of the interaction region of the two glazes are shown and, for context, a picture of the pot.

The background glaze is longquan-iron-shino-MAlk-PSi, the inlay design is glazed with alexanderBowl_0_Z1Y.

The design is created by adhering a mask and then applying the main glaze. After drying, the mask is removed
and the open area filled in with a second glaze, using a bulb syringe with a needle applicator.



Close up Images of the interaction region

full view

full view

full view

full view



Image of the piece

full view

mug with glaze longquan-iron-shino-MAlk-PSi and inlay glaze alexanderBowl_0_Z1Y.

mug is ~4.5 inches in high



oxidation firing to cone 10 in an electric kiln

Firing profiles

Up Fire profile

150 deg F an hour to 250 deg F

400 deg F an hour to 1800 deg F

300 deg F an hour to 2050 deg F

120 deg F an hour to 2310 deg F with a hold of 20 minutes at 2310 deg F

Down Fire Profile

300 deg F an hour to 1750 deg F then a half hour hold at 1750 deg F

300 deg F an hour to 1700 deg F then a Three hour hold at 1700 deg F

25 deg F an hour to 1650 deg F then a one hour hold at 1650 deg F

Clay body is a grolleg porcelain from Tacoma Clay Art Center.



glaze compositions

Background glaze

Empirical Formula longquan-iron-shino-MAlk-PSi :

K2O        0.21
Na2O       0.26
Li2O       0.13
CaO        0.25
MgO        0.15

Al2O3      0.82
Fe2O3      0.21

SiO2       4.21

molecular percent Silica 67.4%



Inlay Glaze

Empirical Formula alexanderBowl_0_Z1Y:

K2O        0.09
Na2O       0.05
CaO        0.70
MgO        0.16

Al2O3      0.43
Fe2O3      0.02

SiO2       2.67

molecular percent Silica 64.7%



Remarks

For these two glazes, the driving force for interaction is the difference in mobility of the two phases
of the matrix glaze together with the difference in composition of the two glazes. The inlay glaze has higher
alkaline earths, lower alumina and silica, and no iron.

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