Reacting glazes at a vertical interface

Glazes interacting at a vertical interface.

The matrix (i.e. background) glaze and inlay glaze do not overlap before firing.
The original mask for the inlay was a simple curved line.

The matrix glaze has a substantially lower silica:alumina ratio than the inlay glaze, as it has a lower
molecular percent of silica and significantly higher molecular percent alumina.

Diffusion of the higher alkali metals of the matrix glaze into the lower alkali metal inlay
is seen in the halo of dark brown framing the inlay; and in the various mottled markings
of the thinner parts of an otherwise ivory inlay glaze.

Several closeups of the interaction region of the two glazes are shown and, for context, a picture of the pot.

The background glaze is longquan-iron-shino-PAl-Z37, the inlay design is glazed with alexanderBowl_0_Z1Y.

The design is created by adhering a mask and then applying the main glaze. After drying, the mask is removed
and the open area filled in with a second glaze, using a bulb syringe with a needle applicator.



Close up Images of the interaction region

full view

full view

full view

full view



Image of the piece

full view

mug with glaze longquan-iron-shino-PAl-Z37 and inlay glaze alexanderBowl_0_Z1Y.

mug is ~4.5 inches in high



oxidation firing to cone 10 in an electric kiln

Firing profiles

Up Fire profile

150 deg F an hour to 250 deg F

400 deg F an hour to 1800 deg F

300 deg F an hour to 2050 deg F

120 deg F an hour to 2310 deg F with a hold of 20 minutes at 2310 deg F

Down Fire Profile

300 deg F an hour to 1750 deg F then a half hour hold at 1750 deg F

300 deg F an hour to 1700 deg F then a Three hour hold at 1700 deg F

25 deg F an hour to 1650 deg F then a one hour hold at 1650 deg F

Clay body is a grolleg porcelain from Tacoma Clay Art Center.



glaze compositions

Background glaze

Empirical Formula longquan-iron-shino-PAl-Z37 :

K2O        0.16
Na2O       0.39
Li2O       0.20
CaO        0.21
MgO        0.04

Al2O3      0.92
Fe2O3      0.12

SiO2       3.56

molecular percent Silica 63.4%



Inlay Glaze

Empirical Formula alexanderBowl_0_Z1Y:

K2O        0.09
Na2O       0.05
CaO        0.70
MgO        0.16

Al2O3      0.43
Fe2O3      0.02

SiO2       2.67

molecular percent Silica 64.7%



Remarks

Note the needle crystals growing in the matrix glaze at the edge of the inlay.

For these two glazes, the driving force for interaction is the difference in mobility of the
matrix glaze and inlay glaze, together with the difference in composition of the two glazes.
The inlay glaze has higher alkaline earths, lower alumina, and no iron.

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