Shifting Edges

A relative of the glaze seen here .

The glaze shown in this note, iron_Alex_0_Z38, has the same silica and alumina as iron_Alex_0PSiMAlk,
but it has less MgO and more alkali metals in its empirical formula.

Both iron_Alex_0_Z38 and iron_Alex_0PSiMAlk feature a glossy matrix with a variety of distinct crystals.
The forms of the micro-crystals in the two glazes are related though not identical.

The matrix of iron_Alex_0_Z38 is variegated, showing a translucent swirled burgundy near the rim, varying
to an opaque orangey brick red, and green confection. In omparison, iron_Alex_0PSiMAlk has a near uniform
brown black glossy matrix.

The nature of the crystals varies equally as that of the matrix. Both glazes have near circular
crystal clusters, acicular crystals, and crystal 'dust', i.e. itsy particle clusters showing no morphological
distinctions, but the crystal surface coverage of Iron_Alex_0PSiMAlk is substantially greater in
iron_Alex_0_Z38.

The most prominent crystals in iron_Alex_0PSiMAlk are the acicular crystals some of which are densely
packed into a distorted hexagonal lattice. The only crystals in iron_Alex_0_Z38 that densely cover a region,
are the coppery colored metallic crystals, which are almost absent from iron_Alex_0PSiMAlk.

The crystal dust in iron_Alex_0PSiMAlk is predominantly dots of microcrystalline iron red.
while in iron_Alex_0_Z38, this 'dust' is coppery colored metallic particles.

To sum up, iron_Alex_0_Z38 has fewer crystals, with greater variety, in a more richly variegated glassy matrix.
Its near neighbor glaze iron_Alex_0PSiMAlk has a surface dominated by a latticework of massed acicular crystals,
with a dusting of red micro-crystals.

Note that the acicular crystals in both glazes show variations in color resulting from absorbing
various oxides from the glaze.

Pictures of the glaze iron_Alex_0_Z38, and close-ups of several of its features, are shown.



Image of the glaze iron_Alex_0_Z38

full view

inside



full view

outside

bowl is ~ 3.5 inches in diameter.



Close up images of glaze texture

full view

full view

full view

full view



oxidation firing to cone 10 in an electric kiln

Firing profiles

Up Fire profile

150 deg F an hour to 250 deg F

400 deg F an hour to 1800 deg F

300 deg F an hour to 2050 deg F

120 deg F an hour to 2310 deg F with a hold of 20 minutes at 2310 deg F

Down Fire Profile

300 deg F an hour to 1750 deg F then a half hour hold at 1750 deg F

300 deg F an hour to 1700 deg F then a Three hour hold at 1700 deg F

25 deg F an hour to 1650 deg F then a one hour hold at 1650 deg F

Clay body is a grolleg porcelain from Tacoma Clay Art Center.



glaze compositions

Empirical Formula iron_Alex_0_Z38 :

K2O        0.09
Na2O       0.42
Li2O       0.15
CaO        0.32
MgO        0.02

Al2O3      0.57
Fe2O3      0.16

SiO2       3.33
P2O5       0.03

molecular percent Silica 65%



Empirical Formula iron_Alex_0PSiMAlk :

K2O        0.07
Na2O       0.33
Li2O       0.15
CaO        0.33
MgO        0.12

Al2O3      0.57
Fe2O3      0.16

SiO2       3.31
P2O5       0.04

molecular percent Silica 65%



Remarks

Each crystal that can grow in a glaze, has the environment in which it grows most readily.

I do not see those coppery metallic crystals in low alkali metal glazes. In this case the higher alkali metal
content of iron_Alex_0_Z38 promotes larger individual crystals, and also the coppery metallic crystals.

Matte microcrystals seem more prevalent in lower alkali metal glazes, and these are seen in iron_Alex_0PSiMAlk.

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