Interacting glazes at a vertical interface

Glazes interacting at a vertical interface.

The matrix (i.e. background) glaze and inlay glaze do not overlap before firing.

The matrix glaze is a microcrystalline matte, as seen in both the close up images, and in the image of the mug.
The inlay glaze also is a microcrystalline matte. It is seen here , with higher iron.

As the background and inlay glaze differ substantially in composition, the micro-crystals which develop
in the two glazes are distinct. In the interface between these two micro-crystalline matte glazes, are seen
crystals not otherwise seen in either glaze. In particular, note the thread-like microcrystals seen
in several of the closeups.

Several closeups of the interaction region of the two glazes are shown and, for context, a picture of the pot.

The background glaze is longquan-iron-shino-Z38-0, the inlay design is glazed with iron_Alex_1MFe

The design is created by adhering a mask and then applying the main glaze. After drying, the mask is removed
and the open area filled in with a second glaze, using a bulb syringe with a needle applicator.



Close up Images of the interaction region

full view

full view

full view

full view



Image of the piece

full view

mug with glaze longquan-iron-shino-Z38-0 and inlay glaze iron_Alex_1MFe.

mug is ~3.5 inches in high



oxidation firing to cone 10 in an electric kiln

Firing profiles

Up Fire profile

150 deg F an hour to 250 deg F

400 deg F an hour to 1800 deg F

300 deg F an hour to 2050 deg F

120 deg F an hour to 2310 deg F with a hold of 20 minutes at 2310 deg F

Down Fire Profile

300 deg F an hour to 1750 deg F then a half hour hold at 1750 deg F

300 deg F an hour to 1700 deg F then a Three hour hold at 1700 deg F

25 deg F an hour to 1650 deg F then a one hour hold at 1650 deg F

Clay body is a grolleg porcelain from Tacoma Clay Art Center.



glaze compositions

Background glaze

Empirical Formula longquan-iron-shino-Z38-0 :

K2O        0.14
Na2O       0.44
Li2O       0.20
CaO        0.17
MgO        0.05

Al2O3      0.97
Fe2O3      0.17

SiO2       3.6

molecular percent Silica 62.6%



Inlay Glaze

Empirical Formula iron_Alex_1MFe:

K2O        0.07
Na2O       0.34
Li2O       0.11
CaO        0.37
MgO        0.11

Al2O3      0.53
Fe2O3      0.08

SiO2       2.97
P2O5       0.02

molecular percent Silica 64.6%



Remarks

The original inlay, as placed in the kiln was a simple curve, about 3/8th of an inch thick. All else is the
result of the erosion of the inlay glaze by flowing/diffusing of the background glaze.

The variously colored crystals near the edge of the interaction region show diffusion of iron and alkali metals
from the background glaze into the inlay crystals.

The troughs cut in the inlay by rivulets of the background glaze are evidence of the background glaze preferentially
eating through the fault lines in the micro-crystalline inlay glaze. In turn, the glossy black regions are the
remains of the background and inlay reacting so completely that a new glaze has emerged.

While melted, both background and inlay glazes are comprised of both liquid and crystals; four components,
all with distinct compositions and mobilities. The interactions between these four different components created the
various effects described above.

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