Increasing Iron

The effect of increasing Iron

A glaze comprised of a glassy matrix with micro-crystalline islands, jingdezhen-iron-3-7, is transformed
into a uniform variegated melt, jingdezhen-iron-3-7-PFe, by a significant increase in Iron.

Iron is amphoteric in cone 10 glazes, meaning it can function as either a flux or a network former. Silica is the
primary network former in ceramic glazes. At cone 10, iron can behave as does silica. As increasing silica,
so also increasing iron, can have the effect seen here, of producing a more uniform melt.

jingdeahen-iron-3-7 is an 'interesting' glaze, yet the glassy matrix is crazed, and the micro-crystalline
islands are not sufficiently spectacular in themselves to make up for that crazing.

jingdezhen-iron-3-7-PFe also has higher phosphorus than jingdezhen-iron-3-7, however I do not think this
is a significant part of the difference between these two glazes.



Image of the low iron glaze jingdezhen-iron-3-7

full view

inside



full view

outside

bowl is ~ 4 inches in diameter.



Image of the high iron glaze jingdezhen-iron-3-7-PFe

full view

inside



full view

outside

bowl is ~ 4 inches in diameter.



oxidation firing to cone 10 in an electric kiln

Firing profiles

Up Fire profile

150 deg F an hour to 250 deg F

400 deg F an hour to 1800 deg F

300 deg F an hour to 2050 deg F

120 deg F an hour to 2310 deg F with a hold of 20 minutes at 2310 deg F

Down Fire Profile

300 deg F an hour to 1750 deg F then a 50 min hold at 1750 deg F

50 deg F an hour to 1700 deg F then a three hour hold at 1700 deg F

25 deg F an hour to 1650 deg F then a one hour hold at 1650 deg F

Clay body is a grolleg porcelain from Tacoma Clay Art Center.



glaze compositions

Empirical Formula jingdezhen-iron-3-7 :

K2O        0.10
Na2O       0.38
Li2O       0.16
CaO        0.29
MgO        0.07

Al2O3      0.60
Fe2O3      0.15

SiO2       3.48
P2O5       0.03

molecular percent Silica 66.2%



Empirical Formula jingdezhen-iron-3-7-PFe :

K2O        0.10
Na2O       0.39
Li2O       0.16
CaO        0.28
MgO        0.07

Al2O3      0.61
Fe2O3      0.23

SiO2       3.5
P2O5       0.05

molecular percent Silica 64.9%



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