Interacting glazes at a vertical interface

Glazes interacting at a vertical interface.

The matrix (i.e. background) glaze and inlay glaze do not overlap before firing.

The matrix glaze is a saturated iron glaze with several distinct crystals.

Several closeups of the interaction region of the two glazes are shown, and additionally for context,
a picture of the pot is shown.

The background glaze is satIron_ZG_Ip7_5_Calcined_Puah_18, the inlay design is glazed with
hankPaper_Z1R_2C_1Var.

The design is created by adhering a mask and then applying the main glaze. After drying,
the mask is removed and the open area filled in with a second glaze, using a bulb syringe
with a needle applicator.



Close up Images of the interaction region

full view

full view

full view

full view

full view



Image of the piece

full view

plate with glaze satIron_ZG_Ip7_5_Calcined_Puah_18 and inlay glaze hankPaper_Z1R_2C_1Var

plate is 10 inches in diameter



oxidation firing to cone 10 in an electric kiln

Firing profiles

Up Fire profile

150 deg F an hour to 250 deg F

400 deg F an hour to 1800 deg F

200 deg F an hour to 2050 deg F

120 deg F an hour to 2310 deg F with a hold of 20 minutes at 2310 deg F

Down Fire Profile

300 deg F an hour to 1750 deg F then a 50 minute hold at 1750 deg F

300 deg F an hour to 1700 deg F then a three hour hold at 1700 deg F

25 deg F an hour to 1650 deg F then a one hour hold at 1650 deg F

Clay body is a grolleg porcelain from Tacoma Clay Art Center.



glaze compositions

Background glaze

Empirical Formula satIron_Ip7_5_Calcined_Puah_18 :

K2O        0.10
Na2O       0.44
Li2O       0.19
CaO        0.17
MgO        0.10

Al2O3      0.72
Fe2O3      0.09

SiO2       3.1
P2O5       0.04

molecular percent Silica 62.3%



Inlay Glaze

Empirical Formula hankPaper_Z1R_2C_1Var:

K2O        0.13
Na2O       0.12
Li2O       0.05
CaO        0.14
MgO        0.01
BaO        0.31
SrO        0.24

Al2O3      0.43

SiO2       2.7
TiO2       0.14

molecular percent Silica 63.4%

Added:

Cobalt Carbonate 1%
Copper Carbonate 0.5%



Remarks

Both the inlay glaze and matrix glaze grow visible crystals, though of distinct composition and morphology.
The result of these contrasting crystals is that the interfacial region has distinct bands radiating out
from the inlay.

The band closest to the inlay, dominated by the inlay, shows a disorganized arrangement of needle crystals in iron
colors, primarily dark brown. These needle crystals most nearly resemble the blue crystals seen in the
central parts of the inlay.

Next is a band of coppery colored acicular crystals, similar to those seen in the matrix glaze.

Surrounding this band of crystals are crystals that belong to the matrix, yet have nucleated at the
edge of this interfacial region; as rock candy grows on a string suspended in a saturated sugar solution.

The matrix glaze, in addition to the large coppery colored acicular crystals, features a dusting of bubble
shaped metallic crystals. The surprise here, showm in the close-up pictures, is that these metallic bubble
crystals are seen atop the acicular crystals.

From this occurrence of these crystals, above, it is clear that the acicular crystals are not on the surface
of the glaze but submerged within the glaze.

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