Interacting glazes at a vertical interface

Glazes interacting at a vertical interface.

The matrix (i.e. background) glaze and inlay glaze do not overlap before firing.

The matrix glaze is a saturated iron aventurine glaze.

Several closeups of the interaction region of the two glazes are shown, and additionally for context,
a picture of the pot is shown.

The background glaze is iron_8_R_C10_13PSi, the inlay design is glazed with
hankPaper_Z1R_2C_1Var.

The design is created by adhering a mask and then applying the main glaze. After drying,
the mask is removed and the open area filled in with a second glaze, using a bulb syringe
with a needle applicator.



Close up Images of the interaction region

full view

full view

full view

full view



Image of the piece

full view

plate with glaze iron_8_R_C10_13PSi and inlay glaze hankPaper_Z1R_2C_1Var

plate is 10 inches in diameter



oxidation firing to cone 10 in an electric kiln

Firing profiles

Up Fire profile

150 deg F an hour to 250 deg F

400 deg F an hour to 1800 deg F

200 deg F an hour to 2050 deg F

120 deg F an hour to 2310 deg F with a hold of 20 minutes at 2310 deg F

Down Fire Profile

300 deg F an hour to 1750 deg F then a 50 minute hold at 1750 deg F

300 deg F an hour to 1700 deg F then a three hour hold at 1700 deg F

25 deg F an hour to 1650 deg F then a one hour hold at 1650 deg F

Clay body is a grolleg porcelain from Tacoma Clay Art Center.



glaze compositions

Background glaze

Empirical Formula iron_8_R_C10_13PSi :

K2O        0.11
Na2O       0.45
Li2O       0.25
CaO        0.17
MgO        0.02

Al2O3      0.56
Fe2O3      0.28

SiO2       3.12

molecular percent Silica 63%



Inlay Glaze

Empirical Formula hankPaper_Z1R_2C_1Var:

K2O        0.13
Na2O       0.12
Li2O       0.05
CaO        0.14
MgO        0.01
BaO        0.31
SrO        0.24

Al2O3      0.43

SiO2       2.7
TiO2       0.14

molecular percent Silica 63.4%

Added:

Cobalt Carbonate 1%
Copper Carbonate 0.5%



Remarks

When observing the close-up pictures, there are sections in which the interaction region has almost
taken over the inlay, yet neither glaze has moved much at all.

Iron has diffused from the matrix glaze into the inlay glaze.

The various colors are likely the result of different diffusivities for the various phases in the inlay glaze.
That is, the iron migrates at different rates, depending on the phase.

Thus, there are different concentrations of iron in each phase, and the color range is the result of the
dynamics of the situation.

Note that simply adding iron to either of the glazes is unlikely to cause the colors seen here.

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