Calcium - Magnesium Balance

Two glazes which differ in the balance of CaO:MgO.

The glaze satIron_ZG_0_Z3J is derived from the glaze satIron_ZG_0_PK_MLi by replacing some CaO with MgO.
If thick, the glaze satIron_ZG_0_Z3J has a dense covering of coppery colored metallic micro-crystals. If thin, as seen
on the outside of the bowl, this glaze has the appearance of a metallic luster. Neither of these effects
are visible in the glaze satIron_ZG_0_PK_MLi.

I show a section of the glaze satIron_ZG_0_PK_MLi, from a piece with a design irrelevant to the present purpose.



Image of the glaze satIron_ZG_0_PK_MLi

full view



Image of the glaze satIron_ZG_0_Z3J

full view

inside

full view

outside

bowl is ~ 4 inches in diameter.



oxidation firing to cone 10 in an electric kiln

Firing profiles

Up Fire profile

150 deg F an hour to 250 deg F

400 deg F an hour to 1800 deg F

300 deg F an hour to 2170 deg F with a hold of 1 hour at 2170 deg F

120 deg F an hour to 2250 deg F

60 deg F an hour to 2270 deg F with a hold of 30 minutes at 2270 deg F

60 deg F an hour to 2310 deg F with a hold of 20 minutes at 2310 deg F

Down Fire Profile

300 deg F an hour to 1750 deg F then a 4 hour hold at 1750 deg F

25 deg F an hour to 1650 deg F then a one hour hold at 1650 deg F

Clay body is a grolleg porcelain from Tacoma Clay Art Center.



glaze compositions

Empirical Formula satIron_ZG_0_PK_MLi :

K2O        0.12
Na2O       0.69
CaO        0.18
MgO        0.01

Al2O3      0.64
Fe2O3      0.22

SiO2       3.23
P2O5       0.10

molecular percent Silica 62.2%



Empirical Formula satIron_ZG_0_Z3J:

K2O        0.11
Na2O       0.69
CaO        0.14
MgO        0.06

Al2O3      0.64
Fe2O3      0.22

SiO2       3.21
P2O5       0.09

molecular percent Silica 62.3%



Remarks

A small amount of MgO in a glaze can substantially change its behavior. The decrease in CaO also is significant
as it decreases the fraction of the Calcium-alumina-silica eutectic in the glaze. An abstruse way of saying that
CaO is a more powerful flux than MgO.

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