Snowflake

Rutile Crystals

These two glazes show rutile crystals on a blue-grey background, the first glaze, hiAlk_Z3P_Z3Q has small
circular clusters of rutile crystals, which I characterize as 'snowflakes'. The second glaze, hiAlk_Z3P_MAl, has in
addition to a small number of snowflakes, a large number of amorphous irregularly shaped regions,
pale grey on the inside, edged in white. Perhaps these are 'melting' snowflakes.

In these two glazes, alumina, as well as the silica:alumina ratio are similar, though not equal. hiAlk_Z3P_Z3Q has
higher silica and alumina, so proportionately less base. It also has less alkali metals because it has higher
MgO and correspondingly lower Na2O than hiAlk_Z3P_MAl.

These glazes are sufficiently different in composition to suggest that rutile crystals can appear in a range of glaze
compositions. Yet I have seen them only in glazes with alumina greater than 0.6, silica:alumina ratio below 6, and
alkali metal:alumina ratio > 0.7.



Image of the glaze hiAlk_Z3P_Z3Q

full view

inside



full view

outside

bowl is ~ 4 inches in diameter.



Image of the glaze hiAlk_Z3P_MAl

full view

inside



full view

outside

bowl is ~ 4 inches in diameter.



oxidation firing to cone 10 in an electric kiln

Firing profiles

Up Fire profile

150 deg F an hour to 250 deg F

400 deg F an hour to 1800 deg F

300 deg F an hour to 2050 deg F

120 deg F an hour to 2310 deg F with a hold of 20 minutes at 2310 deg F

Down Fire Profile

300 deg F an hour to 1850 deg F then a two hour hold at 1850 deg F

300 deg F an hour to 1750 deg F then a one hour hold at 1750 deg F

300 deg F an hour to 1700 deg F then a three hour hold at 1700 deg F

25 deg F an hour to 1650 deg F then a one hour hold at 1650 deg F

Clay body is a grolleg porcelain from Tacoma Clay Art Center.



glaze compositions

Empirical Formula hiAlk_Z3P_Z3Q :

K2O        0.13
Na2O       0.42
CaO        0.35
MgO        0.1

Al2O3      0.65

SiO2       3.63
P2O5       0.06
TiO2       0.19

molecular percent Silica 65.62%



Empirical Formula hiAlk_Z3P_MAl:

K2O        0.12
Na2O       0.51
CaO        0.35
MgO        0.02

Al2O3      0.60

SiO2       3.28
P2O5       0.06
TiO2       0.22

molecular percent Silica 63.43%



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