Several Glazes with Similar UMF

Here are several glazes with nearly the same UMF, sourced from different materials, the differences
in result are large.

What I've been refering to as the Empirical Formula is commonly called the UMF.

The design is created by adhering a mask and then applying the main glaze. After drying,
the mask is removed and the open area filled in with a second glaze, using a bulb syringe
with a needle applicator.



Image of the glaze zincSr_Z3T_PZn_PSi

full view



Image of the glaze zincSr_Z3T_PZn_PSi_0

full view



Image of the glaze zincSr_Z3T_PZn_PSi_1

full view



Image of the glaze zincSr_Z3T_PZn_PSi_2

full view



Image of the glaze zincSr_Z3T_PZn_PSi_3

full view



the third and fourth images are plates ~6 inches in diameter, the others are bowls ~6 inches in diameter.



oxidation firing to cone 10 in an electric kiln

Firing profile - Invert Firing

Up Fire profile cone 10

150 deg F an hour to 250 deg F

400 deg F an hour to 1800 deg F

300 deg F an hour to 2050 deg F

120 deg F an hour to 2310 deg F with a hold of 20 minutes at 2310 deg F

Down Fire Profile cone 10

300 deg F an hour to 1550 deg F then a 1 hr hold at 1550 deg F

300 deg F an hour to 1650 deg F then a 1 hr hold at 1650 deg F

400 deg F an hour to 1750 deg F then a 2 hr hold at 1750 deg F

400 deg F an hour to 1900 deg F then a 3 hr hold at 1900 deg F



Clay body is a grolleg porcelain from Clay Art Center in Tacoma, WA.



glaze composition

Empirical Formula zincSr_Z3T_PZn_PSi:

K2O        0.16
Na2O       0.31
CaO        0.02
MgO        0.17
SrO        0.15
ZnO        0.19

Al2O3      0.52

SiO2       3.20

molecular percent Silica 67.8%

Added:

2.5% Cobalt Carbonate

Recipe zincSr_Z3T_PZn_PSi:

Bentonite 6
EPK_Kaolin 10
Frit_413 18
G_200_EU_Feldspar 50
Magnesium_Carbonate      8
Nepheline_Syenite 72
Silica 14
Strontium_Carbonate 13
Zinc_Oxide 9
cobalt carbonate 5



Empirical Formula zincSr_Z3T_PZn_PSi_0:

K2O        0.15
Na2O       0.31
CaO        0.03
MgO        0.17
SrO        0.16
ZnO        0.18

Al2O3      0.52

SiO2       3.20

molecular percent Silica 67.7%

Added:

2.5% Cobalt Carbonate

Recipe zincSr_Z3T_PZn_PSi_0:

Bentonite 6
G_200 EU Feldspar 30
Magnesium Carbonate      8
Nepheline Syenite 109
Silica 24
Strontium Carbonate 14
Zinc Oxide 9
cobalt carbonate 5



Empirical Formula zincSr_Z3T_PZn_PSi_1:

K2O        0.15
Na2O       0.31
CaO        0.04
MgO        0.14
SrO        0.15
ZnO        0.21

Al2O3      0.52

SiO2       3.26

molecular percent Silica 68.1%

Added:

2.5% Cobalt Carbonate

Recipe zincSr_Z3T_PZn_PSi_1:

Custer Feldspar 74
EPK Kaolin 32
Frit 413 43
Nepheline Syenite 18
Strontium Carbonate      13
Talc 10
Zinc Oxide 10
cobalt carbonate 5



Empirical Formula zincSr_Z3T_PZn_PSi_2:

K2O        0.15
Na2O       0.32
CaO        0.01
MgO        0.18
SrO        0.15
ZnO        0.19

Al2O3      0.52

SiO2       3.24

molecular percent Silica 67.9%

Added:

2.5% Cobalt Carbonate

Recipe zincSr_Z3T_PZn_PSi_2:

Custer Feldspar 80
EPK Kaolin 38
Frit 413 52
Magnesium Carbonate      8
Strontium Carbonate 13
Zinc Oxide 9
cobalt carbonate 5



Empirical Formula zincSr_Z3T_PZn_PSi_3:

K2O        0.15
Na2O       0.32
CaO        0.02
MgO        0.18
SrO        0.14
ZnO        0.19

Al2O3      0.52

SiO2       3.23

molecular percent Silica 67.7%

Added:

2.5% Cobalt Carbonate

Recipe zincSr_Z3T_PZn_PSi_3:

Ball Clay 40
Frit 413 40
G_200 EU Feldspar 59
Magnesium Carbonate      8
Nepheline Syenite 32
Strontium Carbonate 12
Zinc Oxide 9
cobalt carbonate 5



Inlay Glaze:

Empirical Formula inlay hiAlk_Z3P_Z3V_0:

K2O        0.18
Na2O       0.41
CaO        0.31
MgO        0.10

Al2O3      0.64

SiO2       3.54
P2O5       0.07
TiO2       0.21

molecular percent Silica 64.9%



Remarks

The recipes all add to 200, so quantities of individual components can be compared.

I note that the last three glazes zincSr_Z3T_PZn_PSi_1, zincSr_Z3T_PZn_PSi_2, zincSr_Z3T_PZn_PSi_3,
contain substantially higher Frit 413.

These glazes are characterized by micro-crystalline surface crystals growing out of an underlying
glassy matrix. Generally, in this glaze family, small increases in silica result in a greater fraction
of glassy matrix and correspondingly fewer micro-crystals.

The three glazes zincSr_Z3T_PZn_PSi_1, zincSr_Z3T_PZn_PSi_2, zincSr_Z3T_PZn_PSi_3 show
the greater proportion of glassy fraction over micro-crystals that I've observed with small increments
of silica.

Perhaps the silica in the frit is more easily accessible to the glaze than that of the feldspar in
the first two glazes.

Ball Clay contains contaminants that likely are not reported in the analysis, and available
Custer Feldspar analysis have been reported as not entirely reliable. Thus it is likely that the
UMF's of these glazes differ by more than is apparent.

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