glazes interacting at vertical interface

The matrix (i.e. background) glaze and inlay glaze do not overlap before firing.

The matrix glaze is a saturated iron glaze. The inlay glaze is a mixed gloss with microcrystals
containing titanium.

Several closeups of the interaction region of the two glazes are shown, and additionally a closeup
of the matrix glaze. For context, a picture of the pot is shown.

The background glaze is satIron_ZG_Z3N_Z3S, the inlay design is glazed with hiAlk_Z3P_Z3V_0.

The design is created by adhering a mask and then applying the main glaze. After drying,
the mask is removed and the open area filled in with a second glaze, using a bulb syringe
with a needle applicator.



Close up Images of the interaction region

full view

full view

full view

full view



Image of the piece

full view

mug with glaze satIron_ZG_Z3N_Z3S and inlay glaze hiAlk_Z3P_Z3V_0

mug is ~4 inches high



oxidation firing to cone 10 in an electric kiln

Firing profiles

Up Fire profile cone 10

150 deg F an hour to 250 deg F

400 deg F an hour to 1800 deg F

300 deg F an hour to 2050 deg F

120 deg F an hour to 2310 deg F with a hold of 20 minutes at 2310 deg F

Down Fire Profile cone 10

300 deg F an hour to 1650 deg F then a 3 hr hold at 1650 deg F

400 deg F an hour to 1850 deg F then a 2 hr hold at 1850 deg F

300 deg F an hour to 1750 deg F then a 1 hr hold at 1750 deg F

300 deg F an hour to 1700 deg F then a 3 hour hold at 1700 deg F



Clay body is a grolleg porcelain from Clay Art Center in Tacoma, WA.



glaze composition

Empirical Formula satIron_ZG_Z3N_Z3S:

K2O        0.12
Na2O       0.57
CaO        0.29
MgO        0.02

Al2O3      0.76
Fe2O3      0.24

SiO2       3.70
P2O5       0.08

molecular percent Silica 64%



Inlay Glaze:

Empirical Formula inlay hiAlk_Z3P_Z3V_0:

K2O        0.18
Na2O       0.41
CaO        0.31
MgO        0.10

Al2O3      0.64

SiO2       3.54
P2O5       0.07
TiO2       0.21

molecular percent Silica 64.9%



Remarks

The matrix glaze is phase separated with bubbles forming in the glaze and micro-crystals forming
on the surface of these bubbles which then are deposited on the surface. The high titanium inlay
glaze diffuses into the matrix glaze and interacts with these bubbles. The inlay glaze is phase separated
as well. At the interface of these two glazes, the result of the interacting of these phases is a
zone caracterized by tendrils of each glaze penetrating the other.

Oil and vinegar salad dressing is composed of those two phases, the oil and the vinegar, each of which retains
its own identity in the mix. Up to a point, sugar dissolves in coffee, beyond that its a separate phase. Iron
crystals in an over-saturated glaze, like too much sugar in the coffee, a separate phase. Opalescent glazes
can result from liquid separation into distinct phases.

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