glazes interacting at vertical interface

The matrix (i.e. background) glaze and inlay glaze do not overlap before firing.

The matrix glaze is a high alkali metal glaze containing titanium. The inlay glaze contains
strontium, zinc, and cobalt.

Here, we see the reverse pairing of inlay and matrix.
The background glaze containing zinc, strontium and cobalt; the inlay glaze is high in alkali metals
and contains titanium.

Several closeups of the interaction region of the two glazes are shown. For context, a picture of the
pot is shown.

The background glaze is hiAlk_Z3P_M_hAl, the inlay design is glazed with zincSr_Z3S_0.

The design is created by adhering a mask and then applying the main glaze. After drying,
the mask is removed and the open area filled in with a second glaze, using a bulb syringe
with a needle applicator.



Close up Images of the interaction region

full view

full view

full view

full view



Image of the piece

full view

bowl with glaze hiAlk_Z3P_M_hAl and inlay glaze zincSr_Z3S_0

bowl is ~6 inches in diameter



oxidation firing to cone 10 in an electric kiln

Firing profiles

Up Fire profile cone 10

150 deg F an hour to 250 deg F

400 deg F an hour to 1800 deg F

300 deg F an hour to 2050 deg F

120 deg F an hour to 2310 deg F with a hold of 20 minutes at 2310 deg F

Down Fire Profile cone 10

300 deg F an hour to 1650 deg F then a 3 hr hold at 1650 deg F

400 deg F an hour to 1850 deg F then a 2 hr hold at 1850 deg F

300 deg F an hour to 1750 deg F then a 1 hr hold at 1750 deg F

300 deg F an hour to 1700 deg F then a 3 hour hold at 1700 deg F



Clay body is a grolleg porcelain from Clay Art Center in Tacoma, WA.



glaze composition

Empirical Formula hiAlk_Z3P_M_hAl:

K2O        0.13
Na2O       0.49
CaO        0.36
MgO        0.02

Al2O3      0.63

SiO2       3.43
P2O5       0.07
TiO2       0.21

molecular percent Silica 64.31%



Inlay Glaze:

Empirical Formula inlay zincSr_Z3S_0:

K2O        0.10
Na2O       0.30
CaO        0.02
MgO        0.24
SrO        0.15
ZnO        0.19

Al2O3      0.51

SiO2       2.75

molecular percent Silica 64.5%

Added:

2.5% Cobalt Carbonate



Remarks

Both Zinc and titanium glazes will show micro-crystals, especially with long holds. Here, with zinc in the
inlay glaze and titanium in the matrix glaze, there is diffusion of zinc into the matrix, and titanium into the inlay.

It is especially interesting that the matrix glaze completely overran the inlay glaze, which was originally
about 3/8" wide. Instead, the entire design is comprised of the interaction region between the two glazes with
nothing left of the character of the original inlay glaze.

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