glazes interacting at vertical interface

The matrix (i.e. background) glaze and inlay glaze do not overlap before firing.

The matrix glaze is a high alkali metal glaze containing titanium. The inlay glaze is a stiff high calcium
micro-crystalline glaze containing copper and cobalt.

The clash in the interaction region between the distinct micro-crystals which grow in the matrix glaze and
inlay glaze lead to a shingly volcanic appearance in the interaction region.

Several closeups of the interaction region of the two glazes are shown. For context, a picture of the
pot is shown. These closeups are heavily edited to make the artifacts in the interaction region visible.

The background glaze is hiAlk_Z3P_Z3U_0, the inlay design is glazed with vermillionBrick_0MFe.

The design is created by adhering a mask and then applying the main glaze. After drying,
the mask is removed and the open area filled in with a second glaze, using a bulb syringe
with a needle applicator.



Close up Images of the interaction region

full view

full view

full view

full view



Image of the piece

full view

full view

bowl with glaze hiAlk_Z3P_Z3U_0 and inlay glaze vermillionBrick_0MFe

bowl is ~5 inches in diameter



oxidation firing to cone 10 in an electric kiln

Firing profiles

Up Fire profile cone 10

150 deg F an hour to 250 deg F

400 deg F an hour to 1800 deg F

300 deg F an hour to 2050 deg F

120 deg F an hour to 2310 deg F with a hold of 20 minutes at 2310 deg F

Down Fire Profile cone 10

300 deg F an hour to 1650 deg F then a 3 hr hold at 1650 deg F

400 deg F an hour to 1900 deg F then a 3 hr hold at 1900 deg F

300 deg F an hour to 1750 deg F then a 1 hr hold at 1750 deg F

300 deg F an hour to 1700 deg F then a 3 hour hold at 1700 deg F



Clay body is a grolleg porcelain from Clay Art Center in Tacoma, WA.



glaze composition

Empirical Formula hiAlk_Z3P_Z3U_0 :

K2O        0.12
Na2O       0.49
CaO        0.37
MgO        0.02

Al2O3      0.61

SiO2       3.06
P2O5       0.06
TiO2       0.22

molecular percent Silica 61.9%



Inlay Glaze:

Empirical Formula vermillionBrick_0MFe:

K2O        0.07
Na2O       0.11
CaO        0.81
MgO        0.01

Al2O3      0.58

SiO2       2.78

molecular percent Silica 63.6%

Added:

0.5% Cobalt Carbonate
3.0% Copper Carbonate



Remarks

Both high calcium and titanium glazes will show micro-crystals, especially with long holds.
Here, with titanium in the matrix glaze there is diffusion of titanium into the inlay, resulting
in both titanium and calcium crystals in the interfacial region.

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