increasing silica

Here are two glazes, a waxy matte iron yellow glaze with orangy speckles, and a semi-translucent
mottled iron glaze with a multitude of distinct iron precipitates.

The first glaze has the crusty look of a micro-crystalline matte with a large grain size.

The second glaze, ironYellow-PSi differs from the first by an increase in silica. It has a smoother, nearly
silky surface and is a translucent waxy matte if thinly applied. With a higher silica:alumina ratio, it
seems more 'melted' that the lower silica glaze from which it was derived.

Some close-up images are shown for each glaze, and images of the pot.



ironYellow

full view

full view

full view

close ups of glaze ironYellow



full view

full view

ironYellow

bowl is ~3.5 inches in diameter



ironYellow-PSi

full view

full view

full view

close ups of glaze ironYellow-PSi



full view

full view

ironYellow-PSi

bowl is ~3.5 inches in diameter



oxidation firing to cone 10 in an electric kiln

Firing profile for ironYellow

Up Fire profile cone 10

150 deg F an hour to 250 deg F

400 deg F an hour to 1800 deg F

300 deg F an hour to 2050 deg F

120 deg F an hour to 2310 deg F with a hold of 20 minutes at 2310 deg F

Down Fire Profile cone 10

300 deg F an hour to 1650 deg F then a 3 hr hold at 1650 deg F

400 deg F an hour to 1900 deg F then a 3 hr hold at 1900 deg F

300 deg F an hour to 1750 deg F then a 1 hr hold at 1750 deg F

300 deg F an hour to 1700 deg F then a 3 hour hold at 1700 deg F



Firing profile for ironYellow-PSi

Up Fire profile cone 10

150 deg F an hour to 250 deg F

400 deg F an hour to 1800 deg F

300 deg F an hour to 2050 deg F

120 deg F an hour to 2310 deg F with a hold of 20 minutes at 2310 deg F

Down Fire Profile cone 10

300 deg F an hour to 1650 deg F then a 3 hr hold at 1650 deg F

400 deg F an hour to 1850 deg F then a 2 hr hold at 1850 deg F

300 deg F an hour to 1750 deg F then a 1 hr hold at 1750 deg F

300 deg F an hour to 1700 deg F then a 3 hour hold at 1700 deg F



Clay body is a grolleg porcelain from Clay Art Center in Tacoma, WA.



glaze compositions

Empirical Formula ironYellow :

K2O        0.07
Na2O       0.11
CaO        0.81
MgO        0.01

Al2O3      0.53
Fe2O3      0.07

SiO2       2.55

molecular percent Silica 61.5%



Empirical Formula ironYellow-PSi :

K2O        0.07
Na2O       0.11
CaO        0.81
MgO        0.01

Al2O3      0.52
Fe2O3      0.07

SiO2       3.06

molecular percent Silica 65.6%



Remarks

These two glazes were fired in different firings, both firings are 'invert' down-firings, drop to 1650 degF
then up to a higher temperature.

These two firings differ in the temperature and length of time of the high hold that follow the drop to
1650 degF. For the glaze ironYellow, the temperature is 1900 degF and the hold is three hour. For the glaze
ironYellow-PSi, the temperature is 1850 degF and the hold is two hours. That is the only
difference between the two firings. I do not consider that difference significant.

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