cobalt colors in simplified firings

The glaze, zincSr_Z3W_0 in many flavors is
shown here .

The appearance of this glazes is transformed by modifications of the
down-fire holds in the firing. Mixed pinks, lavenders, purples and blues, and even some peach colors
are seen. The micro-crystalline clusters are large and small, intermixed or sharply color segregated.
How does the order and duration of the holds create the many distinct patterns seen above?

As a first attempt to prize apart the many variables, I fired this glaze in four distinct firings, one with
no holds, the others with only one down-hold. The down-fire holds were all of the same four-hour
duration, but occured at different temperatures.

All four firings have the same up-fire protocol.

Firing 1:

No holds - a baseline firing.

Firing 2:

In the down-fire, there is one four hour hold at 1900 degF.

Firing 3:

In the down-fire, there is one four hour hold at 1650 degF.

Firing 4:

In the down-fire, there is one four hour hold at 1750 degF.

The design is a slip trailed contrast glaze applied first to the bisque, subsequently followed
by application of the matrix glaze.



Image of the glaze zincSr_Z3W_0 in Firing 1

full view



Image of the glaze zincSr_Z3W_0 in Firing 2

full view



Image of the glaze zincSr_Z3W_0 in Firing 3

full view



Image of the glaze zincSr_Z3W_0 in Firing 4

full view



The bowls are 5 to 6 inches in diameter.



oxidation firing to cone 10 in an electric kiln

Firing profiles

Firing 1 profile

Up Fire profile cone 10

150 deg F an hour to 250 deg F

400 deg F an hour to 1800 deg F

300 deg F an hour to 2050 deg F

120 deg F an hour to 2310 deg F with a hold of 20 minutes at 2310 deg F

Down Fire Profile cone 10

Turn off kiln.



Firing 2 profile

Up Fire profile cone 10

150 deg F an hour to 250 deg F

400 deg F an hour to 1800 deg F

300 deg F an hour to 2050 deg F

120 deg F an hour to 2310 deg F with a hold of 20 minutes at 2310 deg F

Down Fire Profile cone 10

300 deg F an hour to 1900 deg F then a 4 hr hold at 1900 deg F



Firing 3 profile

Up Fire profile cone 10

150 deg F an hour to 250 deg F

400 deg F an hour to 1800 deg F

300 deg F an hour to 2050 deg F

120 deg F an hour to 2310 deg F with a hold of 20 minutes at 2310 deg F

Down Fire Profile cone 10

300 deg F an hour to 1650 deg F then a 4 hr hold at 1650 deg F



Firing 4 profile

Up Fire profile cone 10

150 deg F an hour to 250 deg F

400 deg F an hour to 1800 deg F

300 deg F an hour to 2050 deg F

120 deg F an hour to 2310 deg F with a hold of 20 minutes at 2310 deg F

Down Fire Profile cone 10

300 deg F an hour to 1750 deg F then a 4 hr hold at 1750 deg F



Clay body is a grolleg porcelain from Clay Art Center in Tacoma, WA.



glaze composition

Empirical Formula zincSr_Z3W_0:

K2O        0.19
Na2O       0.28
CaO        0.02
MgO        0.19
SrO        0.14
ZnO        0.18

Al2O3      0.53

SiO2       3.08

molecular percent Silica 66.8%

Added:

2.5% Cobalt Carbonate



decoration Glaze:

One of hiAlk_Z3P_Z3V_0Mng or hiAlk_Z3P_Z3V_0Munge

Empirical Formula hiAlk_Z3P_Z3V_0Mng:

K2O        0.18
Na2O       0.35
CaO        0.45
MgO        0.02

Al2O3      0.58

SiO2       3.61
P2O5       0.07
TiO2       0.21

molecular percent Silica 65.9%



Empirical Formula hiAlk_Z3P_Z3V_0Munge:

K2O        0.17
Na2O       0.42
CaO        0.31
MgO        0.10

Al2O3      0.61

SiO2       3.50
P2O5       0.07
TiO2       0.18

molecular percent Silica 65.2%



Remarks

I note that the firing with one 4 hour hold at 1750 degF is most like what had been seen in former firings,
yet it doesn't show any of the striking variation seen in prior firings.

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