reversing the order of down-fire holds

The glaze zincSr_Z3W_0 is shown here in several distinct firings.

Those firings had several down-fire holds. To simplify the firing and provide further evidence
that the order of the down-fire holds is a relevant parameter, I fire this glaze in two firings with
only two down-fire holds. In the second firing, the order of the down-fire holds is reversed.

These firings have holds only at the temperatures 1650 degF and 1900 degF.

The glazes in this firing has an underglaze decoration created by slip trailing a
contrast glaze on the bisque before glazing the pot.

I show another glaze ironYellow in these same two firings.

Firing 1:

In the down-fire, there is one four hour hold at 1900 degF, followed by a four hour hold at 1650 degF.

Firing 2:

In the down-fire, there is one four hour hold at 1650 degF, followed by a four hour hold at 1900 degF.

The down-fire of Firing 2 reverses the order of the holds of the down-fire of firing 1.



Image of the glaze zincSr_Z3W_0 in Firing 1

full view

full view



Image of the glaze zincSr_Z3W_0 in Firing 2

full view

full view



Image of the glaze ironYellow in Firing 1

full view

full view



Image of the glaze ironYellow in Firing 2

full view

full view



The bowls glazed with zincSr_Z3W_0 are ~6 inches in diameter. The bowls glazed with
ironYellow are ~3 inches in diameter.



oxidation firing to cone 10 in an electric kiln

Firing profiles

Firing 1 profile

Up Fire profile cone 10

150 deg F an hour to 250 deg F

400 deg F an hour to 1800 deg F

300 deg F an hour to 2050 deg F

120 deg F an hour to 2310 deg F with a hold of 20 minutes at 2310 deg F

Down Fire Profile cone 10

300 deg F an hour to 1900 deg F then a 4 hour hold at 1900 deg F

300 deg F an hour to 1650 deg F then a 4 hour hold at 1650 deg F



Firing 2 profile

Up Fire profile cone 10

150 deg F an hour to 250 deg F

400 deg F an hour to 1800 deg F

300 deg F an hour to 2050 deg F

120 deg F an hour to 2310 deg F with a hold of 20 minutes at 2310 deg F

Down Fire Profile cone 10

300 deg F an hour to 1650 deg F then a 4 hour hold at 1650 deg F

400 deg F an hour to 1900 deg F then a 4 hour hold at 1900 deg F



Clay body is a grolleg porcelain from Clay Art Center in Tacoma, WA.



glaze compositions

Empirical Formula zincSr_Z3W_0:

K2O        0.19
Na2O       0.28
CaO        0.02
MgO        0.19
SrO        0.14
ZnO        0.18

Al2O3      0.53

SiO2       3.08

molecular percent Silica 66.8%

Added:

2.5% Cobalt Carbonate



Empirical Formula ironYellow:

K2O        0.07
Na2O       0.11
CaO        0.81
MgO        0.01

Al2O3      0.53
Fe2O3      0.07

SiO2       2.55

molecular percent Silica 61.5%



Remarks

The glaze zincSr_Z3W_0 in the first firing, with the hold at 1900 degF preceding the hold at 1650 degF,
shows a diffuse dusting of pink particles over much of the glaze, with no strong pinks or strong blues.

By contrast this glaze in the second firing, with the order of the holds reversed, shows a strong
segregation of the pink and blue crystals. There is little of the pink to be seen, yet what there is is sharp,
and the boundary between the pink crystals and the blue crystals is sharp. On the outside,
the pink crystals, where not dense, are seen to have a nearly cellular structure. This is the result of pink
micro-crystals filling in between the large, deeply blue cobalt grains. The surface structure in the second
firing is distinct.

The defect near the bottom left of the bowl from the first firing was caused by a kiln support
accident in unloading.

The glaze ironYellow in the first firing shows distinct green micro-crystalline clusters,
and dark orangey-brown micro-crystals. In the second firing, the green is gone, the micro-crystals are
yellow, with a yellow matrix.

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