a low alkali metal glaze in two firings

Here is a glaze caAlSi_hh_K_PFe which has minimal alkali metals, only that which will be the result
of the impurities present in commonly used ceramic materials.

I show this glaze in a firing with substantial downfire holds, and also in a firing with no downfire
holds, yet with a slow upfire.

Firing 1 has three holds in the downfire, starting with a 4 hour hold at 1600 degF, then a 4 hour
hold at 1900 degF, and finishing with a 4 hour hold at 1650 degF. That is, this downfire has an upfire
in the middle.

Firing 2 achieves cone 10 at 2220 degF, a temperature which is commonly used for cone 6 firings.
It achieves this with a glacially slow upfire for the last 90 degF of the firing. The rate of climb is 13 degF
an hour and, in addition, there is a two hour hold at 2190 degF and another three hour hold at 2220 degF.

This glaze has been fired with several other patterns of downfire holds. Changing the ordering of
the holds at 1650 degF and 1900 degF greatly changes the pattern of the dark brown and green markings, and
the prominence of the iron spots, yet all are recognizably the same glaze. Only replacing downfire
holds with an extremely slow upfire transforms the glaze appreciably.



Image of the glaze caAlSi_hh_K_PFe in Firing 1

full view

full view



Image of the glaze caAlSi_hh_K_PFe in Firing 2

full view

full view



The bowls are respectively ~4 inches in diameter and ~6 inches in diameter.



oxidation firing to cone 10 in an electric kiln

Firing profile 1

Up Fire profile cone 10

150 deg F an hour to 250 deg F

400 deg F an hour to 1800 deg F

300 deg F an hour to 2050 deg F

120 deg F an hour to 2310 deg F with a hold of 20 min at 2310 deg F

Down Fire Profile cone 10

300 deg F an hour to 1650 degF with a hold of 4 hours at 1650 degF.

400 deg F an hour to 1900 degF with a hold of 4 hours at 1900 degF.

300 deg F an hour to 1650 degF with a hold of 4 hours at 1650 degF.



Firing profile 2

Up Fire profile cone 10

150 deg F an hour to 250 deg F

400 deg F an hour to 1850 deg F

120 deg F an hour to 2130 deg F

13 deg F an hour to 2190 deg F / hold 2 hours

13 deg F an hour to 2220 deg F / hold 3 hours

Down Fire Profile cone 10

Turn Kiln Off



Clay body is a grolleg porcelain from Clay Art Center in Tacoma, WA.



glaze compositions

Empirical Formula caAlSi_hh_K_PFe:

K2O        0.005
Na2O       0.005
CaO        0.983
MgO        0.007

Al2O3      0.47
Fe2O3      0.11

SiO2       2.77

molecular percent Silica 63.6%



decoration Glaze:

Empirical Formula hiAlk_Z3P_Z3V_0Mng:

K2O        0.18
Na2O       0.35
CaO        0.45
MgO        0.02

Al2O3      0.58

SiO2       3.61
P2O5       0.07
TiO2       0.21

molecular percent Silica 65.9%



Remarks

The second bowl has a splash of a high rutile decoration glaze beneath the primary glaze on the
inside of the bowl.

In the first firing, there is a prominent greyed green phase, and the iron markings are a strong brown.
In that second firing, the green is entirely gone, and the markings are not so sharply edged, rather
blending into each other.

The texture of the glaze in the second firing is rather different, this is most easily seen in the manner
in which the highlights are fuzzed out, rather than sharply reflective. In that first firing, the glaze
surface is smooth and hard, but in the second softly textured and that pot feels smooth to the fingers.

Does that second bowl, where the glaze crawled over the rutile decorative glaze have a curled up
cat asleep within it?

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