glazes interacting at vertical interface

The matrix (i.e. background) glaze and inlay glaze do not overlap before firing.

The matrix glaze is a high alkali metal glaze containing titanium. The inlay glaze is a micro-crystalline glaze
high in silica and low in alumina containing copper, cobalt and zirconia.

Cross diffusion of the matrix glaze into the inlay and the inlay into the matrix glaze creates contrasting
bands of reactions, with the growth of diverse crystals.

The alkalis of the matrix diffuse into the inlay, the silica and alkaline earths correspondingly
move into the matrix glaze.

Several closeups of the interaction region of the two glazes are shown. For context, a picture of the
pot is shown. These closeups are heavily edited to make the artifacts in the interaction region visible.

The background glaze is hiAlk_Z3P_MAl; the inlay design is glazed with oribe-woof-MAlk-PPSi.

The design is created by adhering a mask and then applying the main glaze. After drying,
the mask is removed and the open area filled in with a second glaze, using a bulb syringe
with a needle applicator.



Close up Images of the interaction region

full view

full view

full view



Image of the piece

full view

bowl with glaze hiAlk_Z3P_MAl and inlay glaze oribe-woof-MAlk-PPSi

bowl is ~6 inches in diameter



oxidation firing to cone 10 in an electric kiln

Firing profiles

Up Fire profile cone 10

150 deg F an hour to 250 deg F

400 deg F an hour to 1800 deg F

300 deg F an hour to 2050 deg F

120 deg F an hour to 2310 deg F with a hold of 20 minutes at 2310 deg F

Down Fire Profile cone 10

300 deg F an hour to 1850 deg F then a 2 hr hold at 1850 deg F

300 deg F an hour to 1750 deg F then a 1 hr hold at 1750 deg F

300 deg F an hour to 1700 deg F then a 3 hr hold at 1700 deg F

25 deg F an hour to 1650 deg F then a 1 hour hold at 1650 deg F



Clay body is a grolleg porcelain from Clay Art Center in Tacoma, WA.



glaze composition

Empirical Formula hiAlk_Z3P_MAl :

K2O        0.12
Na2O       0.51
CaO        0.35
MgO        0.02

Al2O3      0.60

SiO2       3.28
P2O5       0.06
TiO2       0.22

molecular percent Silica 63.4%



Inlay Glaze:

Empirical Formula oribe-woof-MAlk-PPSi:

K2O        0.08
Na2O       0.03
CaO        0.72
MgO        0.17

Al2O3      0.29

SiO2       3.45
P2O5       0.01

molecular percent Silica 72.5

Added:

2% Cobalt Carbonate
5.0% Copper Oxide
5% Zircopax



Remarks

With titanium, calcium, phosphorus and zirconium, there are ample sources for the micro-crystals seen in the
interaction region. The dark cloud surrounding the inaly could be diffusion of either copper or cobalt into the matrix glaze.

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